钒渣物理力学性能研究

Кажущаяся Плотность Металловключений, Извлеченных, ИЗ Ванадиевого Шлака, Очищенных ОТ Шлака
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摘要

钒渣的生产和提钒工艺是一项费时费力的工艺,这决定了钒渣的物理、力学和工艺性能研究的现状,影响了钒渣加工利用的有效性。在提钒过程中使用氧化硅质添加剂(OSA)作为稀释剂,可以保证VS中基本组分的含量(技术规范ТУ 14-11-187-86)。然而,它改变了渣组分中金属夹杂物的化学和矿物组成及分布,因此所有的研究参数都是通过有OSA和没有OSA的变量来考虑的。给出了VS的平均化学成分、矿物相含量和金属夹杂物含量。结果表明,现有的金属夹杂物含量测定方法不能保证结果的可重复性。提出了一种流体静力称重法评价金属夹杂物结渣的方法。此外,还研究了OSA对钒渣物理力学性能的影响。测定了矿渣中金属含量与表观密度的关系,提高了运输设施、地堡、仓库等容量计算的准确性。通过添加OSA和不添加OSA获得的样品,完成了VS强度特性的研究,这对于正确选择破碎和研磨设备非常重要。结果表明,不含OSA的VS强度明显高于含OSA的VS,可破碎性指标较低。添加OSA的VS更容易机械加工-在破碎,研磨。此外,在这种情况下,金属夹杂物较好地打开,在从渣中提取时,它们的渣较少。
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Study of physical and mechanical properties of vanadium slag
Technology of vanadium slag (VS) production and extraction vanadium out of it is money- and labor-consuming process, that stipulates the actuality of study of physical, mechanical and technological properties of VS and influences the effectiveness of its processing and utilization. It was noted, that the oxidizing-siliceous addition (OSA), used as a dilutant in the process of vanadium extraction, enables to ensure basic components content in the VS accounting the Technical Specifications ТУ 14-11-187–86. However, it changes the chemical and mineral compositions and distribution of metal inclusions by slag fractions, therefore all the studied parameters were considered by variants with the OSA and without it. The averaged chemical composition of VS, its mineral phases content and metal inclusions content presented. It was shown, that existing methods of evaluation of metal inclusions content in the VS do not ensure repeatability of the results. A methodology was proposed to evaluate slagging of metal inclusions by the hydrostatic weighing method. Besides, Influence of OSA on physical and mechanical properties of vanadium slag. A dependence of metal content in slag on its apparent density determined, which will increase accuracy of calculations of capacity of transport facilities, bunkers, warehouses etc. The study of the VS strength characteristics, knowledge of which is important for correct choice of crushing and grinding equipment, was accomplished with samples obtained with additions OSA and without OSA. The results obtained showed, that the strength of the VS without OSA is significantly higher, and the indices of crushability is lower, comparing with VS with OSA utilization. The VS with OSA additions is mechanical processed easier – at crushing, grinding. Besides, in this case the metal inclusions are opened better and during extraction out of a slag they are less slaggy.
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