生物浸出在铜浮选尾矿中的应用

M. Sydykanov, Yerkin Bektay, Gaukhar Turysbekova, A. Baibatsha, Gurhan Yalcin
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引用次数: 0

摘要

铜含量丰富的新矿床的缺乏和旧矿床的枯竭,以及必须遵守环境要求,引起了需要处理冶金工业尾矿的问题。在哈萨克斯坦积累了大量的“Borgezsay”和“Staroye”尾矿。尾矿储量估计可达10亿吨。样品评价表明,尾矿中铜的平均含量为0.15 ~ 0.2%。超过100万吨的铜储存在这些尾矿中。矿物结构的复杂性贯穿于这些废物的浸出过程。研究了几种硫酸浸出工艺。用黄铜矿作催化剂或氯化物溶解的方法都不经济有效。对铜的生物浸出进行了研究。微生物破坏各种金属矿物质,确保金属过渡到浸出液中。采用酸性氧化亚铁硫杆菌。这些铁氧化细菌的菌株在硫细菌中占有特殊的地位,因为除了由于硫化合物氧化而自养生长的能力外,它们还可以利用亚铁氧化的能量。研究表明,使用这些细菌可以将样品中的铜含量从0.2%降低到0.05%,在某些情况下甚至可以降低到0.005%。对多种尾矿样品进行了生物浸出试验,结果表明该方法是有效的。
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APPLICATION OF BIOLEACHING OF COPPER FLOTATION TAILINGS
The lack of new deposits with a rich copper content and the depletion of old deposits, as well as the need to comply with environmental requirements, raises the issue of the need to process the tailings of metallurgical industries. In Kazakhstan was accumulated significant stocks of tailings "Borgezsay" and "Staroye". The tailings reserves are estimated at up to 1 billion tons. Sample evaluation showed that the average copper content in the tailings is 0.15-0.2%. More than 1 million tons of copper are stored in this tailings. The complexity of the structure of minerals passes through the process of leaching of these wastes. Several types of leaching in sulfuric acid were considered for processing. Methods using chalcopyrite as a catalyst or dissolution with chlorides were not economically efficient. Studies have been carried out on the use of copper bioleaching. Bioorganisms destroy various minerals of metals, ensures the transition of metals into the leaching solution. Thionic bacteria Acidithiobacillus ferrooxidans were used. The strains of these iron-oxidizing bacteria occupy an exceptional position among thionic bacteria, since in addition to the ability to autotrophic growth due to the oxidation of sulfur compounds, they can use the energy of oxidation of ferrous iron. Studies have shown that the use of these bacteria can reduce the copper content in samples from 0.2% till 0.05%, in some cases down to 0.005%. Bioleaching carried out on various tailings samples showed the effectiveness of this method.
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