气体理想性的热力学方面

Paulo Victor Ferreira da Silva, Orivaldo Da Silva Lacerda Junior
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引用次数: 0

摘要

这项工作以系统和有组织的方式处理气体理想性的热力学方法。介绍了关于气体的行为及其性质的重要方面,例如物质的物理状态的性质,其中气体根据其分子的排列处于最简单的状态。会议强调了一些主题,这些主题使科学家们通过他们观察到的实验结果得出了目前可用的知识,从而得出了经验定律,这些定律有助于理解气体在不同情况下的行为,例如温度和压力的变化。这些定律按比例组合在一起,形成了一个数学方程,称为完美气体或理想气体方程,这个定律严格遵循公式化的经验数学关系,它是推断什么是真正的理想气体或完美气体的起点。所引用的气体模型是气体动力学理论的基础,该理论在解释理想气体的行为方面有很成熟的理论认识。在这项工作中还暴露了实际气体的定义,由于分子之间可能发生的相互作用,实际气体表现出与理想气体不同的行为。为了更好地理解实际气体,我们解释了研究这些气体分子间力的方法,如压缩系数和范德华方程。此外,还讨论了气体状态下发生的转化,如液化。本工作是在文献研究的基础上进行的,以便从热力学的角度对气体的研究有一个有利的认识,目的是为研究物质的相建立必要的定义。
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THERMODYNAMIC ASPECTS OF GASES IDEALITY
This work deals with a thermodynamic approach to the ideality of gases in a systematic and organized way. Important aspects are presented regarding the understanding of the behavior of gases and their properties, such as the properties of the physical state of matter, in which the gas is in the simplest state according to the arrangement of its molecules. It was highlighted the topics that led the scientists to arrive at the knowledge currently available, through experimental results observed by them, resulting in empirical laws that helped to understand the behavior of the gases in diverse situations, as in the cases of variations of temperature and pressure. These laws, which combined proportionately, resulted in a mathematical equation called the perfect or ideal gas equation, a law that strictly follows the formulated empirical mathematical relations and which is the starting point for the deduction of what is really the ideal or perfect gas. The gas model quoted is the basis of the kinetic theory of gases, which theory has a well-developed theoretical understanding to explain the behavior of an ideal gas. Also exposed in this work is the definition of real gases that present different behavior of the ideal gases due to the interactions that can occur between their molecules. For a better understanding of the real gases we explained ways of studying the intermolecular forces in these gases, such as the compressibility factor and the Van der Waals equation. Also, the transformations occurring in the gaseous state, such as liquefaction, are discussed. The present work was done on the basis of bibliographical research in order to have a favorable knowledge about the study of gases from the thermodynamic point of view, aiming to establish the necessary definitions of the study of the phases of matter.
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