第七章。水动力和声空化作用下的绿色合成程序

G. Cravotto, S. Tagliapietra, Zhilin Wu
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引用次数: 1

摘要

本章旨在通过描述无害和绿色的空化技术来促进有机合成的进一步发展,这些技术非常适合于多相和催化反应。流体动力空化和超声波创造了独特的高能微环境及其伴随的热点、冲击波、微射流和剪切力。除了突出的传质和机械化学效应外,高活性中间自由基的形成可以启动在经典条件下不会发生的机械路径。
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CHAPTER 7. Green Synthetic Procedures under Hydrodynamic and Acoustic Cavitation
This chapter aims to stimulate further progress in organic synthesis by describing harmless and green cavitational technologies that are well suited to heterogeneous-phase and catalysed reactions. Hydrodynamic cavitation and ultrasound create unique high-energy microenvironments and their accompanying hot-spots, shock-waves, micro-jets and shear forces. In addition to outstanding mass transfer and mechanochemical effects, the formation of highly reactive, intermediate radical species can initiate mechanistic paths that do not occur under classical conditions.
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