液体/固体相变点无机盐导热系数的测定

Zhang Shuiqing, Wu Ye, Z. Jiemin, Yang Ying, Li Yannan, Li Shujuan
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引用次数: 2

摘要

根据熔融和凝固过程中移动界面速度与两相热物理性质的关系,设计了一种测定无机盐导热系数的测量装置。以硝酸钠为样品,对其熔点的导热系数进行了测定。然而,在相变室中很难实现一维传导,这导致了解析解的热物性数据的不准确性。因此采用了实验测试与数值模拟相结合的方法。将硝酸钠导热系数的实验结果和校正结果与参考文献推荐值进行比较,误差分别小于9%和2%。
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Determination of Thermal Conductivity of Inorganic Salts at the Liquid/Solid Phase Transition Point
Based on the relationship between the speed of the moving interface and the thermophysical properties of two phases during melting and solidification processes, a measuring apparatus was designed to determine the thermal conductivity of inorganic salts. Using sodium nitrate as the sample, an experiment was carried out to determine its thermal conductivity at the melting point. However, it was difficult to realize the one-dimensional conduction in phase change chamber, which caused the inaccuracy of the data of thermophysical properties from the analytical solutions. So the combination of experiment test and numerical simulation was applied. Compared the experimental result and corrective result of thermal conductivity of sodium nitrate with the value recommended in reference errors are less than 9%and 2%.
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