[由高折射锗酸玻璃和氧化铝晶体组成的牙科瓷的强度和透明度]。

M Kon
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摘要

研制了一种用于牙科的半透明铝瓷。研究了折射率和烧结性能对高折射率锗酸玻璃(na20 - tio2 - geo2)和氧化铝晶粉组成的铝瓷透明度和强度的影响。在1300℃左右熔接得到了各种高折射率的锗酸盐玻璃试样。熔接后的Na2O-TiO2-GeO2玻璃试样的折射率为1.64 ~ 1.76,随TiO2含量的增加而增大。采用80 wt%锗酸玻璃和20 wt%氧化铝在580 ~ 820℃的致密化温度下制成烧结铝瓷,高折射率锗酸玻璃制备的烧结铝瓷与其他铝瓷相比具有较高的透明度,其透明度与商业长石瓷(体)几乎相同。不同折射率的铝瓷由于在玻璃基体结晶后产生晶体,其透明度低于没有结晶的铝瓷。弯曲强度值为120 MPa,与相同氧化铝体积含量的玻璃-氧化铝陶瓷的弯曲强度值相近。未结晶铝瓷比结晶铝瓷具有更高的强度。
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[Strength and transparency of dental porcelain consisting of high refractive germanate-glass and alumina crystal].

A translucent aluminous porcelain was developed for dentistry. The effects of refractive indexes and sintering behaviors on transparency and strength of the aluminous porcelains consisting of high refractive germanate-glass (Na2O-TiO2-GeO2) and alumina crystal powders were examined. The various germanate-glass specimens with a high refractive index were made by fusion at about 1,300 degrees C. The refractive indexes of fused Na2O-TiO2-GeO2 glass specimens were 1.64-1.76, heightened with an increasing TiO2 content. The sintered aluminous porcelains were made from the mixed compacts consisting of 80 wt% germanate-glass and 20 wt% alumina at the densification temperature of 580-820 degrees C. Sintered aluminous porcelains prepared with high refractive germante-glass had a high transparency compared with the other aluminous porcelains, with almost the same transparency as a commercial feldspathic porcelain (body). Aluminous porcelains had lower transparency with different refractive index due to generation of crystals following the crystallization of glass matrix than that without crystallizing property. Bending strength value was 120 MPa, which is similar to that for the glass-alumina ceramics with the same content of alumina volume as germanate-glass aluminous porcelains. Non-crystallized aluminous porcelain had a higher strength compared with the crystallized one.

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