含能材料老化寿命预测模型

Yongfei Pan, F. Nan, P. Chen
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引用次数: 0

摘要

含能材料由于暴露于自然环境或特定的工作环境中,在加工、储存或使用过程中容易受到热、氧、光等因素的影响,容易发生物理或化学变化,导致材料性能退化甚至无法使用。因此,如何准确预测含能材料的老化寿命,选择合适的试验方法,降低现有老化试验的成本就显得尤为重要。基于化学动力学理论,介绍了材料老化性能P、老化时间t和老化温度t之间的内在关系,综述了含能材料安全贮存寿命预测的数学模型和计算方法。包括常用的Arrhenius方程、Berthelot方程、修正Arrhenius方程、经典线性关系法、P-t-T数学模型法、蒙特卡罗模拟等方法,讨论了数学模型的特点和可行性,建立了模型实现的程序流程。为材料老化寿命预测软件的开发做了准备,方便了生产实践,提高了预测效率。
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Aging Life Prediction Model of Energetic Materials
Because of exposure to natural environment or specific working environment, energetic materials are easily affected by heat, oxygen, light and other factors in the process of processing, storage or use, and are prone to physical or chemical changes, resulting in degradation of material properties and even unusable. Therefore, how to accurately predict the aging life of energetic materials, choose appropriate test methods, and reduce the cost of existing aging test is particularly important. Based on chemical kinetics theory, this paper introduces the internal relationship between material aging performance P, aging time t and aging temperature T, and reviews the mathematical model and calculation method for predicting the safe storage life of energetic materials. Including the commonly used Arrhenius equation, Berthelot equation, modified Arrhenius equation, classical linear relation method, P-t-T mathematical model method, Monte Carlo simulation and other methods, discusses the characteristics and feasibility of mathematical model, establish the program flow of model implementation. It makes preparation for the development of a material aging life prediction software, and also facilitates production practice and improves the prediction efficiency.
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