禽死灰作为磷基肥料的利用潜力

İ. Acar
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引用次数: 0

摘要

由于家禽业的扩大,全球产生了大量的家禽垃圾。从几种替代技术中,对这种废物的最可行的管理方法之一是燃烧,其排出的主要副产品是家禽垃圾灰(PLA)。本研究考察了聚乳酸样品作为磷基肥料原料的利用潜力。实验结果表明,PLA样品中Ca、P和K的含量分别为29.54%、6.13%和4.96%。虽然样品中锌含量为2472 ppm,铜含量为922 ppm,但浸出试验确定的溶解度低于危险废物的毒性限值。在主要元素方面,渗滤液中Ca含量约为290 mg/l, pH值大于13,P含量仅为0.0092 mg/l。这两个关键的结果构成了直接使用PLA作为肥料的主要困难。另一方面,通过酸化、重金属去除和中和等工艺,可获得重金属含量低、pH值中性的富p产品。但是,在这种情况下,应从经济角度仔细考虑所采用的方法的可行性。综上所述,未经任何预处理,不可能直接将PLA样品作为P基肥料施用,这主要是由于PLA样品的碱度非常高,而P的水溶性很低。
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Utilization Potential of Poultry Litter Ash as Phosphorus-Based Fertilizer
A large quantity of poultry litter is globally generated as a result of expanding poultry industry. From several alternative technologies, one of the most feasible management for this waste is combustion, which exhausts poultry litter ash (PLA) as the main by-product. In this study, a PLA sample was examined for its utilization potential as a raw material for phosphorus-based fertilizer. According to the experimental results, Ca, P and K were determined as the major elements in the PLA sample with 29.54, 6.13 and 4.96%, respectively. Although the sample contains 2472 ppm Zn and 922 ppm Cu, their solubility determined by the leaching test is below the toxicity limit for hazardous waste. In terms of the major elements, about 290 mg/l Ca was detected in the leachate, resulting in a pH value higher than 13, whereas P concentration was found only 0.0092 mg/l. These two crucial results constitute the major difficulties for direct use of the PLA as a fertilizer. On the other hand, a usable P-rich product with low heavy metal contents and neutral pH can be obtained through acidification, heavy metal removal and neutralization processes. However, in this case, the feasibility of processes to be used should be carefully considered in economic point of view. In conclusion, direct application of the PLA sample examined as P-based fertilizer is not possible without any pre-treatments mainly due to its very high alkalinity and the low water solubility of P.
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