用丝网印刷方法表征用于太阳能电池的氧化铜的结构和光学性质

Yahaya Abubakar Aliero, Umar Abdullahi Bello, Mamuda Salihu, A. Ahmad
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摘要

采用丝网印刷技术研究了用于太阳能电池的氧化铜的结构和光学性质。为了测试温度效应,采用了退火程序。样品分别在150℃和200℃退火30分钟,最后样品在室温下干燥。利用扫描电子显微镜(SEM)、紫外-可见光谱和傅里叶变换红外光谱(FTIR)对材料进行了表征。结果表明,退火温度对样品的结构性能有较大的影响。SEM分析表明,150℃退火后的CuO试样形貌良好,无脆性和裂纹,晶粒间无间隙。采用Cary 50bio (0906m12)型紫外可见光谱仪对样品在室温下的吸收率和透射率进行分析,干燥CuO样品和150℃退火样品在可见光波段的吸收率最强。FTIR结果表明,整个样品在太阳能应用中具有良好的透射率。在150℃下退火的CuO样品具有1.29eV的带隙,使其成为太阳能应用的良好材料。
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Characterization of the Structural and Optical Properties of Copper Oxide for Use in Solar Cells Using Screen Printing Method
Structural and optical properties of copper oxide for solar cells applications was studied using screen printing techniques. Annealing procedure was employed in order to test the temperature effect. Samples were annealed at 150 oC and 200 oC for 30 minutes, the last sample was allowed to dry at room temperature. Scanning Electron Microscopy (SEM), UV-visible spectroscopy, and Fourier transforms infrared spectroscopy were used to describe the materials (FTIR). The results demonstrate that the annealing temperature had a substantial impact on the sample's structural properties. SEM analysis shows that the 150 oC annealed CuO sample have good morphology, no brittleness or cracking, and no gaps between crystal grains. The UV-visible spectrometer machine type Cary 50bio (0906m12) was used to analyze the absorption and percentage transmittance of the samples at room temperature, dry CuO sample and sample annealed at 150 oC have the strongest absorption in the visible band. The entire samples have a good transmittance for solar applications according to FTIR results. CuO sample annealed at 150 oC has a band gap 1.29eV which makes it good material for solar applications.
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