V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karachevtsev
{"title":"用作气体传感器衬底的铋酸玻璃","authors":"V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karachevtsev","doi":"10.1007/s10717-023-00607-4","DOIUrl":null,"url":null,"abstract":"<div><div><p>Bismuthate-borate glasswas synthesized with the compositions (wt.%) 70 Bi<sub>2</sub>O<sub>3</sub>, 2 GeO<sub>2</sub>, 25 B<sub>2</sub>O<sub>3</sub>, 3 MoO<sub>3</sub>; 70 Bi<sub>2</sub>O<sub>3</sub>, 17 GeO<sub>2</sub>, 10 B<sub>2</sub>O<sub>3</sub>, 3 MoO<sub>3</sub> and 80 Bi<sub>2</sub>O<sub>3</sub>, 4 GeO<sub>2</sub>, 5 MoO<sub>3</sub>, 11 SiO<sub>2</sub>; 80 Bi<sub>2</sub>O<sub>3</sub>, 8 GeO<sub>2</sub>, 8.5 SiO<sub>2</sub>, 3.5 MoO<sub>3</sub>. Methods were developed for forming a receptor layer on the resulting glass by means of ultrasonic spraying of the interacting components and applying a water-insoluble polymer film obtained via a chemical reaction between the polymer poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride and the modifier potassium hexacyanoferrate (II). The sensors prepared based on these glasses make it possible to determine to within2– 4% the content of hydrogen sulfide and water vapor in air.</p></div></div>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"80 7-8","pages":"317 - 321"},"PeriodicalIF":0.6000,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bismuthate Glass as Backing for Gas Sensors\",\"authors\":\"V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karachevtsev\",\"doi\":\"10.1007/s10717-023-00607-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>Bismuthate-borate glasswas synthesized with the compositions (wt.%) 70 Bi<sub>2</sub>O<sub>3</sub>, 2 GeO<sub>2</sub>, 25 B<sub>2</sub>O<sub>3</sub>, 3 MoO<sub>3</sub>; 70 Bi<sub>2</sub>O<sub>3</sub>, 17 GeO<sub>2</sub>, 10 B<sub>2</sub>O<sub>3</sub>, 3 MoO<sub>3</sub> and 80 Bi<sub>2</sub>O<sub>3</sub>, 4 GeO<sub>2</sub>, 5 MoO<sub>3</sub>, 11 SiO<sub>2</sub>; 80 Bi<sub>2</sub>O<sub>3</sub>, 8 GeO<sub>2</sub>, 8.5 SiO<sub>2</sub>, 3.5 MoO<sub>3</sub>. Methods were developed for forming a receptor layer on the resulting glass by means of ultrasonic spraying of the interacting components and applying a water-insoluble polymer film obtained via a chemical reaction between the polymer poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride and the modifier potassium hexacyanoferrate (II). The sensors prepared based on these glasses make it possible to determine to within2– 4% the content of hydrogen sulfide and water vapor in air.</p></div></div>\",\"PeriodicalId\":579,\"journal\":{\"name\":\"Glass and Ceramics\",\"volume\":\"80 7-8\",\"pages\":\"317 - 321\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2023-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass and Ceramics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10717-023-00607-4\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass and Ceramics","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10717-023-00607-4","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Bismuthate-borate glasswas synthesized with the compositions (wt.%) 70 Bi2O3, 2 GeO2, 25 B2O3, 3 MoO3; 70 Bi2O3, 17 GeO2, 10 B2O3, 3 MoO3 and 80 Bi2O3, 4 GeO2, 5 MoO3, 11 SiO2; 80 Bi2O3, 8 GeO2, 8.5 SiO2, 3.5 MoO3. Methods were developed for forming a receptor layer on the resulting glass by means of ultrasonic spraying of the interacting components and applying a water-insoluble polymer film obtained via a chemical reaction between the polymer poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride and the modifier potassium hexacyanoferrate (II). The sensors prepared based on these glasses make it possible to determine to within2– 4% the content of hydrogen sulfide and water vapor in air.
期刊介绍:
Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.