环境友好型壳聚糖基木材/木材复合胶粘剂研究进展

Prajyot Dhawale, Sainath Gadhave, Ravindra V. Gadhave
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摘要

由于世界能源问题和对石油资源的依赖,重点已经转向寻找新的、可持续的木材粘合剂原料来源。可再生生物聚合物将逐渐取代石油和天然气作为木材胶粘剂的主要原料。壳聚糖是一种储量丰富的生物质物质。壳聚糖具有生物可降解性、生物相容性和无毒性等优点,是胶粘剂领域最具吸引力的生物聚合物之一。壳聚糖及其衍生物在粘合剂的广泛应用中引起了人们的极大兴趣。然而,在正常潮湿的条件下,它的粘合强度不足以粘合木材。关于如何使壳聚糖基胶粘剂具有更强的粘结性和耐水性,已经进行了大量的研究。为了有效地将壳聚糖基木胶用于木/木复合胶粘剂中,使其具有与合成胶粘剂相当的性能,人们开发了许多新的方法。它通过添加各种交联剂进行改性,包括醛类如乙二醛戊二醛等,环氧化合物,与其他聚合物共混,不同的酸和壳聚糖接枝到乙酸乙烯酯上。在木质复合材料的生产中,壳聚糖还可以清除甲醛。本文综述了壳聚糖基木材胶粘剂的各种交联剂,以改善壳聚糖基木材胶粘剂的性能。
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Environmentally Friendly Chitosan-Based Wood/Wood Composite Adhesive: Review
Due to the world’s energy issues and dependency on petroleum resources, focus has switched to finding new, sustainable raw material sources for wood adhesives. Renewable biopolymers would gradually replace petroleum and natural gas as the primary raw materials used in wood adhesives. Chitosan is a biomass substance having a lot of reserves. Chitosan is one of the most fascinating biopolymers in the adhesive sector because of its potential qualities for adhesive applications, such as biodegradability, biocompatibility, and non-toxicity. Chitosan and its derivatives have so garnered considerable interest in a wide range of adhesive applications. However, its adhesive strength is insufficient to glue wood under normal, humid conditions. There has been a lot of study done on how to make chitosan-based adhesives more cohesive and water resistant. In order to effectively use chitosan-based wood glue in wood/wood composite adhesive that gives comparable performance to synthetic adhesives, numerous new ways have been developed. It has been modified by the addition of various cross-linkers, including aldehydes like glyoxal glutaraldehyde etc., epoxy compounds, blended with other polymers, different acids and chitosan grafted onto vinyl acetate. In the production of wood composites, chitosan can also scavenge formaldehyde. This review of chitosan-based adhesives focuses on various cross-linkers for chitosan modification in order to improve the properties of chitosan-based wood adhesives.
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