2,3,3-三甲基- 3h -吲哚胺偶氮染料的合成

Tinatin Bukia, Mariam Utiashvili, Manana Tsiskarishvili, Sopo Jalalishvili, Ana Gogolashvili, Tamara Tatrishvili, Gia Petriashvili
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引用次数: 0

摘要

合成了以2,3,3-三甲基- 3h -吲哚胺为基料的新型偶氮化合物,并通过红外光谱、核磁共振和质谱分析对其进行了表征。通过三种不同的合成途径:1)用Zn/NaOH在醇中还原硝基化合物;2)在甲苯中MnO2的存在下加热2,3,3-三甲基- 3h -吲哚胺-5-胺;3)将2,3,3-三甲基- 3h -吲哚胺-5-胺重氮化,并用合适的偶联剂处理所得重氮盐。
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Synthesis of Some Azo Dyes Based on 2,3,3-Trimethyl-3H-indolenine
New azo compounds on the base of 2,3,3-trimethyl-3H-indolenine were synthesized and characterized by FT-IR, NMR, and Mas-spectral analysis. The synthesis was conducted in three different pathways: 1) by reducing the nitro compound with Zn/NaOH in alcohol; 2) by heating of 2,3,3-trimethyl-3H-indolenine-5-amine in the presence of MnO2 in toluene, and 3) by diazotization of 2,3,3-trimethyl-3H-indolenine-5-amine and treating the resulting diazonium salt with the appropriate coupler.
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