几种羧酸四乙基铵盐离子液体的合成

Muna Raad Mahmood, Mehdi Salih Shihab
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引用次数: 0

摘要

成功合成了2-(4-羧基苯基)氨甲酰苯甲酸四乙基铵、B1、4-氧-4-(吡啶-3-氨基)-2-丁酸四乙基铵、B2、2-((4-氨甲基苯基)氨甲酰苯甲酸四乙基铵、B3、4-((4-氨甲基苯基)氨基)-4-氧丁酸四乙基铵等有机铵盐离子液体。通过FTIR、1H-NMR和13C-NMR等光谱技术,确定了有机盐类的结构。差示扫描量热法(DSC)热分析表明了有机铵盐(B1-B4)的热稳定性。与NaCl相比,在水溶液中发现了高导电性。
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Synthesis of Some Carboxylate Tetraethylammonium Salts as Ionic Liquids
Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.
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