{"title":"几种羧酸四乙基铵盐离子液体的合成","authors":"Muna Raad Mahmood, Mehdi Salih Shihab","doi":"10.22401/anjs.26.3.01","DOIUrl":null,"url":null,"abstract":"Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.","PeriodicalId":7494,"journal":{"name":"Al-Nahrain Journal of Science","volume":"58 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Some Carboxylate Tetraethylammonium Salts as Ionic Liquids\",\"authors\":\"Muna Raad Mahmood, Mehdi Salih Shihab\",\"doi\":\"10.22401/anjs.26.3.01\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.\",\"PeriodicalId\":7494,\"journal\":{\"name\":\"Al-Nahrain Journal of Science\",\"volume\":\"58 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Al-Nahrain Journal of Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22401/anjs.26.3.01\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Al-Nahrain Journal of Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22401/anjs.26.3.01","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of Some Carboxylate Tetraethylammonium Salts as Ionic Liquids
Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.