研究锰掺杂对硫化锌结构、形貌和光学性能的影响

IF 0.6 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Indian Journal of Pure & Applied Physics Pub Date : 2023-01-01 DOI:10.56042/ijpap.v61i9.3490
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引用次数: 0

摘要

利用水热法合成了未掺杂和mn掺杂的ZnS,并利用x射线衍射(XRD)、x射线能谱(EDX)、场发射扫描电镜(FE-SEM)、傅里叶变换红外光谱(FT-IR)和紫外可见光谱对其进行了表征。XRD谱图证实了纳米颗粒的立方闪锌矿晶体结构。由于Mn的掺杂,所有样品的晶粒尺寸都有所增加。FE-SEM图像显示合成样品呈球形形貌。EDX光谱证实了掺杂样品中Mn的存在。FTIR光谱显示掺杂改变了Zn-S吸收带的位置。随着掺杂率从0到10%的增加,吸收最大值出现红移,带隙减小。
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To Study the Impact of Mn Doping on Structural, Morphological and Optical Properties of Zinc Sulfide
By utilising hydrothermal approach undoped and Mn-doped ZnS was synthesized and characterized by using X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), Field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FT-IR) and UV-Visible spectroscopy. The XRD pattern confirmed the cubic sphalerite crystal structure of prepared nanoparticles. Due to Mn doping, size of crystallite for all the samples was increased. FE-SEM images showed spherical morphology of synthesized samples. The EDX spectrum confirms the presence of Mn in the doped sample. FTIR spectrum showed that doping shifts the position of Zn-S absorption band. A red shift was observed in the absorption maxima and the bandgap was decreased with increasing doping percentage from 0 to 10%.
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
42
审稿时长
7 months
期刊介绍: Started in 1963, this journal publishes Original Research Contribution as full papers, notes and reviews on classical and quantum physics, relativity and gravitation; statistical physics and thermodynamics; specific instrumentation and techniques of general use in physics, elementary particles and fields, nuclear physics, atomic and molecular physics, fundamental area of phenomenology, optics, acoustics and fluid dynamics, plasmas and electric discharges, condensed matter-structural, mechanical and thermal properties, electronic, structure, electrical, magnetic and optical properties, cross-disciplinary physics and related areas of science and technology, geophysics, astrophysics and astronomy. It also includes latest findings in the subject under News Scan.
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