过渡金属催化反应合成单取代烯烃的乙烯基酯和乙烯基磺酸盐的绿色替代品

Q3 Chemistry Chemistry Pub Date : 2023-10-20 DOI:10.3390/chemistry5040153

Tomáš Tobrman

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引用次数: 0

摘要

综述了乙烯基磺酸盐和醋酸乙烯酯在交叉偶联反应中作为绿色替代品的应用。第一部分简要介绍了乙烯基磺酸盐的制备及其交叉偶联反应。然后，简要回顾了醋酸乙烯酯的交叉偶联反应，包括环化反应、藤波-森谷反应和转乙烯基化反应。

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Vinyl Esters and Vinyl Sulfonates as Green Alternatives to Vinyl Bromide for the Synthesis of Monosubstituted Alkenes via Transition-Metal-Catalyzed Reactions

This review summarizes the applications of vinyl sulfonate and vinyl acetate as green alternatives for vinyl bromide in cross-coupling reactions. In the first part, the preparation of vinyl sulfonates and their cross-coupling reactions are briefly discussed. Then, a brief review of vinyl acetate cross-coupling reactions, including cyclization reactions, the Fujiware–Moritani reaction, and transvinylation reactions are described.

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来源期刊

Chemistry

CiteScore

2.50

自引率

0.00%

发文量

审稿时长

11 weeks

期刊介绍： Chemistry—A European Journal is a truly international journal with top quality contributions (2017 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields.