具有嗅觉作用的物质的排放源危险分类的卫生理由

Ol’ga V. Budarina, Zul’fiya F. Sabirova, Il’ya B. Andryushin, Zinaida V. Shipulina
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引用次数: 0

摘要

这项研究的目的是对与嗅觉暴露源相关的行业进行比较分析和排名,这取决于它们排放的气味的“冒犯性”。材料和方法。使用ECOMA TO-8动态嗅觉计对15种物质混合物(超过4200次测量)进行了实验性嗅觉-气味测定研究,这些物质代表或模拟了来自以下行业的排放:刨花板、大豆和油菜籽中的植物油、咖啡、香水和化妆品、食品调味品、烟草制品,以及畜牧业、气体恶臭和燃料油蒸汽处理。使用计算机软件Probit Analysis (v.4.0)进行统计数据处理。使用FOCUS GC-DSQ-II型色谱质谱仪对排放物中所含物质的混合物进行了分析研究。结果。根据对与气味来源有关的生产和工艺过程的样本和排放模型进行的嗅觉-气味测定研究,并建立气味的检测阈值和物质的“令人讨厌”阈值,建议根据气味的“令人讨厌”(“令人讨厌的潜在”)(极令人讨厌、令人讨厌、中等令人讨厌和轻微令人讨厌),对设施进行危害分类。这使得可以根据SanPiN 2.2.1./ 2.1.1.1200-03(新版)和俄罗斯联邦首席国家卫生医生于2022年2月28日颁布的法令更新当前的分类n7 . 的局限性。该研究的局限性与使用相对较新的实验方法来呈现气味刺激及其注册有关,这需要额外的测试,以及在将排放样品运送到实验室期间可能发生的物质转化。 结论。对各类企业和市政设施排放的多组分恶臭物质混合物进行实验恶臭评价的方法,可以根据恶臭排放的“刺激性”(或“恼人潜力”)标准,快速、合理地优化现有的行业分类。
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Hygienic justification for the classification of the danger of sources of emissions of substances having an olfactorial action
The purpose of the study is a comparative analysis and ranking of industries related to sources of olfactory exposure, depending on the odour’s “offensiveness” of their emissions. Material and methods. Experimental olfacto-odourimetric studies were carried out using a dynamic olfactometer ECOMA TO-8 on the example of fifteen mixtures of substances (over 4200 measurements) representing or simulating emissions from the industries including particle boards, vegetable oil from soybean and rapeseed seeds, coffee, perfumery and cosmetic products, food flavourings, tobacco products, as well as livestock operations, gas odourizing, and fuel oil steam treatment. Statistical data processing was performed using the computer software Probit Analysis (v.4.0). Analytical study of mixtures of substances contained in emissions was carried out using a FOCUS GC-DSQ-II chromato-mass spectrometer. Results. Based on the conducted olfacto-odourimetric studies of samples and models of emissions from the productions and technological processes related to sources of odour with the establishment of odour’s detection thresholds and the “offensiveness” thresholds of substances, a facilities’ hazard classification is proposed taking into account the odour’s “offensiveness” (“annoyance potential”) of emissions (extremely offensive, offensive, moderately offensive and slightly offensive), which makes it possible to update the current classification according to SanPiN 2.2.1./2.1.1.1200–03 (new edition) and the Decree of the Chief State Sanitary Doctor of the Russian Federation dated February 28, 2022 N 7. Limitations. The study’s limitations associated with the use of a relatively new experimental method for the presentation of odour stimuli and their registration, which requires additional testing, as well as with the possible transformation of substances during the delivery of emission samples to the laboratory. Conclusion. The methodology of the experimental odourimetric evaluation of multicomponent mixtures of odorous substances that are part of the emissions of various enterprises and municipal facilities makes it possible to quickly and rationally optimize the existing classification of industries according to the “offensiveness” criterion (or “annoyance potential”) of the odorous emissions.
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来源期刊
Gigiena i sanitariia
Gigiena i sanitariia Environmental Science-Pollution
CiteScore
0.80
自引率
0.00%
发文量
192
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