螺旋松合成醋酸纤维素(<i>Pandanus tectorius</i>)提高PVDF膜透水性和抗污性的叶片

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY Indonesian Journal of Chemistry Pub Date : 2023-10-16 DOI:10.22146/ijc.85726
Elyna Wahyu Trisnawati, Venty Suryanti, Edi Pramono, Indri Sri Cahyani, Diah Safriyani
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引用次数: 0

摘要

从天然资源中不断开发纤维素衍生物,寻找性能最佳的疏水聚合物基膜技术。以松叶纤维素为原料合成醋酸纤维素(CA)填料,对聚偏氟乙烯(PVDF)膜的亲水性、性能和防污性能进行了研究。采用Fischer酯化法合成CA,以0.3%的CA浓度采用相转化法制备PVDF膜。FTIR分析表明,CA在1700 cm−1处的吸收表明纤维素的羟基已被酯基(C=O)成功取代,CA具有3.50的高取代度(DS)值。添加CA可使PVDF膜的亲水性和抗污性能提高86.45%。此外,CA膜的透水性比原始PVDF膜提高了2-3倍。CA的存在增强了PVDF膜的孔隙率,提高了膜对MB的过滤效果。结果表明,从螺旋松叶纤维素中提取的CA作为PVDF膜的填料和潜在的染料过滤材料具有广阔的应用前景。
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Synthesis of Cellulose Acetate from Screw Pine (<i>Pandanus tectorius</i>) Leaves for Enhancing Water Permeability and Fouling Resistance of PVDF Membrane
Cellulose derivatives from natural resources continuously develop to find the best hydrophobic polymer-based membrane technology performance. This study was conducted to improve the hydrophilicity, performance, and anti-fouling of polyvinylidene fluoride (PVDF) membrane with cellulose acetate (CA) filler synthesized from screw pine (Pandanus tectorius) leaf cellulose. CA was synthesized by the Fischer esterification mechanism and the PVDF membrane was fabricated using the phase inversion method with 0.3% CA concentration. FTIR analysis of CA shows an absorption at 1700 cm−1 suggesting that the hydroxyl group of cellulose had been successfully substituted with an ester group (C=O), and CA has a high degree of substitution (DS) value of 3.50. Adding CA improved the hydrophilicity and anti-fouling properties of up to 86.45% of PVDF membranes. Furthermore, CA increased the value of water permeability 2–3 times than pristine PVDF membrane. The presence of CA enhanced the porosity of the PVDF membrane, which promoted the membrane's effectiveness for MB filtering. As a result, CA from screw pine leaf cellulose has promising features as a filler for PVDF membranes and potential dye filtration.
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来源期刊
Indonesian Journal of Chemistry
Indonesian Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
2.30
自引率
11.10%
发文量
106
审稿时长
15 weeks
期刊介绍: Indonesian Journal of Chemistry is a peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry, including educational chemistry, applied chemistry, and chemical engineering.
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