苯并三唑衍生物的合成及其对合成润滑油抗氧化性能的影响

A.А. Gadirov, E.A. Nagiyeva, V.M. Farzaliev
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引用次数: 0

摘要

合成了新型N-(芳基(烷基芳基)氨基甲基)-1,2,3-苯并三唑,研究了其在合成润滑油中的抗氧化性能。所得化合物的结构经IR和NMR确证。研究了N-(芳基(烷基芳基)氨基甲基)-1,2,3-苯并三唑作为合成润滑油的添加剂。以季戊四醇酯和C5-C9馏分的合成脂肪酸(PEE)为合成油。根据GOST 236797-79的标准方法,在225℃的温度下,在钢、铝和铜板存在下,研究了合成化合物对合成润滑油热氧化稳定性的影响。结果表明,所制得的抗氧化剂明显延缓了酯类油的氧化过程,其效率优于著名的抑制剂苯基-α萘胺。
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Synthesis of benzotriazole derivatives and their effect on antioxidant properties of synthetic lubricant oil
New N-(aryl(alkylaryl)aminomethyl)-1,2,3-benzotriazoles have been synthesized and their antioxidant properties in the composition of synthetic lubricating oil have been studied. The structure of the obtained compounds was confirmed by IR and NMR spectroscopy. N-(aryl(alkylaryl)aminomethyl)-1,2,3-benzotriazoles were investigated as additives to synthetic lubricating oils. An ester of pentaerythritol and synthetic fatty acids of the C5-C9 fraction (PEE) was used as a synthetic oil. Effect of synthesized compounds on thermooxidative the stability of synthetic lubricating oil was studied standard method volume oxidation according to GOST 236797-79, for 20 hours at a temperature of 225 ° C, in the presence of steel, aluminum and copper plates. It has been shown that the obtained antioxidants noticeably delay the process of oxidation of ester oils and are superior in efficiency to the well-known inhibitor phenyl-α naphthylamine.
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