Anastasievsko-Troitskoe油田弱转化原油沥青质、树脂和酸热裂解产物中烃类分布的比较

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-12-07 DOI:10.1134/S0965544123060130
G. N. Gordadze, A. V. Vasileva, D. S. Vylekzhanina, G. A. Gadzhiev, O. A. Stokolos
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引用次数: 0

摘要

采用气相色谱-质谱联用技术研究了Anastasievsko-Troitskoe油田(地平线IV)低成熟原油中烃类生物标志物(正构烷烃、异戊二烷、甾烷和萜烷)和adamantane系列烃类的分布规律,以及该油田沥青质、树脂和酸的热裂解产物。高分子质量油前体的热裂解产生与初始油中相同的碳氢化合物(hc),以及原金刚烷(金刚烷的前体)。金刚烷系列烃没有形成,它们在该原油中的存在是由于它们来自其他油源地层的供应。实验表明,初始油中少量的正构烷烃在较苛刻的条件下被释放。
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Comparison of the Hydrocarbon Distribution in Thermolysis Products of Asphaltenes, Resins, and Acids Isolated from Weakly Transformed Crude Oil from the Anastasievsko-Troitskoe Oil Field (Horizon IV)

Regular trends in the distribution of hydrocarbon biomarkers (n-alkanes, isoprenanes, steranes, and terpanes) and hydrocarbons of the adamantane series in low-maturity crude oil from the Anastasievsko-Troitskoe oil field (horizon IV) and in products formed by thermolysis of asphaltenes, resins, and acids from this oil were studied by gas chromatography–mass spectrometry. Thermolysis of high-molecular-mass oil precursors yields the same hydrocarbons (HCs) as those present in the initial oil, and also protoadamantanes (precursors of adamantanes). HCs of the adamantane series are not formed, and their presence in this crude oil is due to their supply from other oil source strata. The experiments show that the n-alkanes present in the initial oil in small amounts are released under more severe conditions.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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