改性聚对苯二甲酸乙酯废物修补环氧砂浆的粘弹性和力学性能

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series A Pub Date : 2023-11-23 DOI:10.1134/s0965545x23701183
Chor. Wayakron Phetphaisit, Wanwisa Singthong, Saranagon Hemavibool, Polphat Ruamcharoen
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引用次数: 0

摘要

摘要对难分解塑料追求可持续循环利用的理念,为其他产品增值。以环氧低聚物、胺和改性PET废硬化剂为原料,配以砂,制备了适用于建筑修补的新型环氧砂浆。采用三种端羧基PET (CTPET)作为共硬化剂,与一种胺类化合物共同制备了新型复合连锁环氧砂浆。粘弹性研究表明,ctpet影响了玻璃态和橡胶平台的储存模量,表明环氧基与砂集料之间的界面粘附。此外,CTPET的加入提高了材料的阻尼性能和玻璃化温度。此外,CTPET中酯基的结合键可能有助于提高环氧砂浆的抗压强度和抗折强度。研究了其在溶液中浸泡后的吸收和弯曲变化,以及与普通水泥基材料的界面弯曲结合强度。
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Viscoelastic and Mechanical Properties of Repair Epoxy Mortar from Modified Poly(ethylene terephthalate) Waste

Abstract

The idea of sustainable and circular utilization of difficult to decompose plastics is pursued to add value to other products. New epoxy mortars suitable for construction repair made from epoxy oligomer, amine and modified PET waste hardeners mixed with sand were prepared. Three types of carboxyl terminated PET (CTPET) were used as co-hardeners, along with an amine, to prepare new combination linkage epoxy mortars. Investigation of the viscoelastic properties revealed that the CTPETs influenced the storage modulus at glassy state and the rubbery plateau, indicative of interfacial adhesion between the epoxy matrix and sand aggregates. Additionally, the damping behavior and glassy temperature were increased with the addition of CTPET. Moreover, the combination linkage of ester groups from the CTPET likely contribute to the enhancement of compressive strength and flexural strength in the epoxy mortar. The results of absorption and flexural change after immersion in solution, as well as the interfacial flexural bonding strength with ordinary cement-based material were also investigated.

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来源期刊
Polymer Science, Series A
Polymer Science, Series A 化学-高分子科学
CiteScore
1.70
自引率
0.00%
发文量
55
审稿时长
3 months
期刊介绍: Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
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