Yanyan Que , Wenli Lei , Yin Fang , Shuzhong He , Yang Chen
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Recent advances in (4 + 3) cycloaddition of allenes
Allenes are a class of unsaturated compounds containing a propadiene structural moiety, exhibiting essential physiological, pharmacological, and various reactivities. Their (4 + 3) cycloaddition reaction has become an effective method for synthesizing seven-membered rings, especially for heterocycles. This method has been continuously improved and developed. Herein, we review the (4 + 3) cycloaddition of allenes, focusing on the developed methodologies and the outlook in this field from 2013 to 2023.
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