{"title":"Eu2+ 激活的硫代镓酸盐荧光粉的光致发光特性","authors":"Young-Sik Cho, Moon-Su Bok, Young-Duk Huh","doi":"10.1002/bkcs.12805","DOIUrl":null,"url":null,"abstract":"<p>This work analyzes the crystal structural properties and photoluminescence properties of six Eu<sup>2+</sup>-activated thiogallates: CaGa<sub>2</sub>S<sub>4</sub>:Eu<sup>2+</sup>, SrGa<sub>2</sub>S<sub>4</sub>:Eu<sup>2+</sup>, EuGa<sub>2</sub>S<sub>4</sub>, BaGa<sub>2</sub>S<sub>4</sub>:Eu<sup>2+</sup>, Sr<sub>2</sub>Ga<sub>2</sub>S<sub>5</sub>:Eu<sup>2+</sup>, and Eu<sub>2</sub>Ga<sub>2</sub>S<sub>5</sub>. Photoluminescence parameters such as the absorption energy (<i>E</i><sub>abs</sub>), emission energy (<i>E</i><sub>em</sub>), zero-phonon line energy (<i>E</i><sub>0</sub>), Stokes shift (Δ<i>S</i>), and red shift (<i>D</i>) are discussed. This work is the first report on the photoluminescence parameters of these six Eu<sup>2+</sup>-activated thiogallates and therefore provides important information about these materials.</p>","PeriodicalId":54252,"journal":{"name":"Bulletin of the Korean Chemical Society","volume":"45 2","pages":"157-164"},"PeriodicalIF":1.7000,"publicationDate":"2023-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photoluminescence properties of Eu2+-activated thiogallate phosphors\",\"authors\":\"Young-Sik Cho, Moon-Su Bok, Young-Duk Huh\",\"doi\":\"10.1002/bkcs.12805\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This work analyzes the crystal structural properties and photoluminescence properties of six Eu<sup>2+</sup>-activated thiogallates: CaGa<sub>2</sub>S<sub>4</sub>:Eu<sup>2+</sup>, SrGa<sub>2</sub>S<sub>4</sub>:Eu<sup>2+</sup>, EuGa<sub>2</sub>S<sub>4</sub>, BaGa<sub>2</sub>S<sub>4</sub>:Eu<sup>2+</sup>, Sr<sub>2</sub>Ga<sub>2</sub>S<sub>5</sub>:Eu<sup>2+</sup>, and Eu<sub>2</sub>Ga<sub>2</sub>S<sub>5</sub>. Photoluminescence parameters such as the absorption energy (<i>E</i><sub>abs</sub>), emission energy (<i>E</i><sub>em</sub>), zero-phonon line energy (<i>E</i><sub>0</sub>), Stokes shift (Δ<i>S</i>), and red shift (<i>D</i>) are discussed. This work is the first report on the photoluminescence parameters of these six Eu<sup>2+</sup>-activated thiogallates and therefore provides important information about these materials.</p>\",\"PeriodicalId\":54252,\"journal\":{\"name\":\"Bulletin of the Korean Chemical Society\",\"volume\":\"45 2\",\"pages\":\"157-164\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-12-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of the Korean Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/bkcs.12805\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of the Korean Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/bkcs.12805","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Photoluminescence properties of Eu2+-activated thiogallate phosphors
This work analyzes the crystal structural properties and photoluminescence properties of six Eu2+-activated thiogallates: CaGa2S4:Eu2+, SrGa2S4:Eu2+, EuGa2S4, BaGa2S4:Eu2+, Sr2Ga2S5:Eu2+, and Eu2Ga2S5. Photoluminescence parameters such as the absorption energy (Eabs), emission energy (Eem), zero-phonon line energy (E0), Stokes shift (ΔS), and red shift (D) are discussed. This work is the first report on the photoluminescence parameters of these six Eu2+-activated thiogallates and therefore provides important information about these materials.
期刊介绍：
The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.
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