利用猪笼草绿色合成氧化铜纳米粒子及其抗氧化和光催化应用

Gamze TOPAL CANBAZ
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引用次数: 0

摘要

利用猪笼草提取物,采用廉价、简便、有效的绿色合成方法制备了氧化铜纳米粒子(CuO NPs)。通过傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、能量色散 X 射线(EDX)和 X 射线衍射仪(XRD)分析方法测定了纳米颗粒的形状、结合力和晶体结构。扫描电子显微镜分析表明颗粒呈球形,能量色散 X 射线分析表明 Cu 和 O 的元素组成为 Cu 58.17 % 和 O 32.73 %。傅立叶变换红外光谱分析确定了 Cu-O 键结构。在 XRD 分析中,观察到了定义 CuO NPs 的峰值。研究了合成的 CuO NPs 的抗氧化性和光催化活性。抗氧化能力的检测范围为 50-500 μg/mL。在浓度为 500 μg/mL 时,纳米粒子的自由基清除活性为 70.75%。在光催化研究中,研究了活性红 120(RR 120)染料的降解。经计算,30 分钟内的降解率为 76%。
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Green Synthesis of CuO Nanoparticles Using Tragopogon porrifolius and Their Antioxidant and Photocatalytic Applications
Copper oxide nanoparticles (CuO NPs) were produced by green synthesis method which is a cheap, easy and effective method using Tragopogon porrifolius extract. The shape, bond and crystal structure of the nanoparticles were determined by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and X-ray diffractometer (XRD) analysis methods. SEM analysis showed that the particles were spherical and EDX analysis showed the elemental composition of Cu and O as Cu 58.17 % and O 32.73 %. Cu-O bond structure was identified in FTIR analysis. In XRD analysis, peaks defining CuO NPs were observed. The antioxidant and photocatalytic activity of the synthesized CuO NPs were investigated. Antioxidant capacities were examined in the range of 50-500 μg/mL. The free radical scavenging activity of the nanoparticles was determined as 70.75 % at a concentration of 500 μg/mL. In photocatalytic studies, Reactive Red 120 (RR 120) dye degradation was investigated. The degradation time was calculated as 76 % in 30 min.
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