用蛭石合成 NaY 沸石并用表面活性剂改性

T. R. B. Barros, T. S. B. Barbosa, Meiry Gláucia Freire Rodrigues
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引用次数: 0

摘要

这项工作的重点是利用替代硅源制备 NaY 沸石,并用表面活性剂十六烷基三甲基溴化铵对沸石进行改性。研究采用了两种不同的水热合成路线:一种是以硅酸钠为硅源的传统方法,另一种是以蛭石粘土为硅源的可持续方法。在传统的沸石合成中,硅酸钠通常被用作二氧化硅的来源。然而,.对蛭石进行酸处理,然后进行初级处理以获得二氧化硅。利用离子交换法,用有机表面活性剂 CTABr 对 NaY 沸石进行改性。 根据各种表征技术,可以验证通过常规路线和可持续路线获得的 NaY 沸石保持了结构特性。他们采用可持续途径合成 NaY 沸石,从而获得了一种合成成本低、性质与传统合成方法相似的材料。在使用表面活性剂十六烷基三甲基溴化铵(CTABr)进行改性后,NaY沸石的结构得以保持,这证明了沸石结构的稳定性和改性过程的高效性。
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NaY Zeolite Synthesis from Vermiculite and Modification with Surfactant
This work focuses on preparing NaY zeolite using alternative sources of silica and modifying the zeolite with the surfactant cetyltrimethylammonium bromide. Two different hydrothermal synthesis routes were employed: the conventional method using sodium silicate as the silica source, and the other is a sustainable approach using vermiculite clay as the silica source. In traditional zeolite synthesis, sodium silicate is often used as the source of silica. However, . The vermiculite was subjected to an acid treatment, followed by a primary treatment to obtain silica. Using the ion exchange method, the NaY zeolite was modified by an organic surfactant CTABr. Based on the various characterization techniques, it was possible to verify the obtaining of NaY zeolite through the conventional and sustainable routes, in which the structural properties were maintained. They used the sustainable path to synthesize NaY zeolite, which allowed for obtaining a material with low synthesis cost and properties similar to those synthesized conventionally. The structures of the NaY zeolites were maintained after the modification process with the surfactant Cetyltrimethylammonium Bromide (CTABr), demonstrating the structural stability of the zeolites and the efficiency of the modification process.
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