yag 陶瓷粉研磨条件对光学陶瓷性能的影响

V. E. Suprunchuk, A. A. Kravtsov, V. Lapin, V. Tarala, L. V. Tarala, E. V. Medyanik, F. Malyavin
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摘要

本研究考虑了在不同研磨条件下前驱体粉末和 YAG 陶瓷粉末的形态和团聚程度的变化。评估了这些参数对陶瓷光学特性和结构的影响。YAG 前驱体粉末是通过化学共沉淀获得的。使用扫描电子显微镜、激光衍射分析、X 射线相分析和布鲁瑙尔-艾美特-泰勒气体吸附法对其形态、团聚体和结晶的大小进行了评估。研究发现,研磨 YAG 前驱体粉末可以降低陶瓷粉末的团聚程度。研究发现,在研磨球与前驱体粉末的质量比为 6.75/1 和研磨介质与前驱体粉末的质量比为 4.5/1 时,可以实现最佳模式。因此,通过化学沉淀法合成的粉末使用额外的研磨阶段以及研磨模式的选择,可以改善 YAG 光学陶瓷的性能。
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INFLUENCE OF YAG CERAMIC POWDERS GRINDING CONDITIONS OF ON THE PROPERTIES OF OPTICAL CERAMICS
In this study, the changes in the morphology and degree of agglomeration of both precursor powders and ceramic YAG powders under varying grinding conditions was considered. The effect of these parameters on the optical properties and structure of the ceramics was assessed. The YAG precursor powders were obtained through chemical co-precipitation. The morphology, size of agglomerates, and crystallites was evaluated using scanning electron microscopy, laser diffraction analysis, X-ray phase analysis, and Brunauer–Emmett–Teller gas adsorption. It was found that milling the YAG precursor powders allows for a reduction in the degree of agglomeration of the ceramic powders. It was discovered that optimal modes can be achieved at a mass ratio of grinding balls to precursor powder of 6.75/1 and a ratio of the mass of the grinding medium to the mass of the precursor powder of 4.5/1. These modes provide the necessary granulometric characteristics and the highest monodispersity. Therefore, it has been demonstrated that the use of an additional milling stage for powders synthesized by chemical precipitation, along with the selection of milling modes, can improve the properties of YAG optical ceramics.
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