电化学水冷却剂净化动力学模型

IF 0.4 4区 工程技术 Q4 NUCLEAR SCIENCE & TECHNOLOGY Atomic Energy Pub Date : 2024-01-05 DOI:10.1007/s10512-023-01030-2
A. L. Shimkevich
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引用次数: 0

摘要

在一个电化学电池中,包括一个基于吸附过滤器的平衡金属毡阳极和一个表面积小得多的高极化阴极,氢氧根阳离子和氢氧根阴离子在阴极表面附近水冷却液的粘性子层中形成双电层。如果阴极电势允许这些离子之间进行电子交换,那么双电层就会成为羟基自由基的强大来源,而羟基自由基在阴极外具有化学活性。然后,当水性冷却剂流经该池时,痕量放射性核素杂质将被吸附在可再生的金属毡表面上,并不断被羟基自由基氧化,从而被提取出来。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Kinetic model of electrochemical aqueous coolant decontamination

In an electrochemical cell comprising an equilibrium metal felt anode based on a sorption filter, as well as a highly polarized cathode having a significantly smaller surface area, hydroxonium cations and hydroxide anions form a double electric layer in a viscous sublayer of the aqueous coolant near the cathode surface. If the cathode electric potential allows for an electron exchange between these ions, then the double layer becomes a powerful source of hydroxyl radicals, which are chemically active outside the cathode. Then, when the aqueous coolant flows through this cell, trace radionuclide impurities will be extracted from it by the adsorption on a renewable surface of a metal felt, continuously oxidized by hydroxyl radicals.

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来源期刊
Atomic Energy
Atomic Energy 工程技术-核科学技术
CiteScore
1.00
自引率
20.00%
发文量
100
审稿时长
4-8 weeks
期刊介绍: Atomic Energy publishes papers and review articles dealing with the latest developments in the peaceful uses of atomic energy. Topics include nuclear chemistry and physics, plasma physics, accelerator characteristics, reactor economics and engineering, applications of isotopes, and radiation monitoring and safety.
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