肟的化学探险

IF 0.8 4区化学 Q4 CHEMISTRY, ORGANIC Arkivoc Pub Date : 2024-01-07 DOI:10.24820/ark.5550190.p012.112

Samir Z. Zard

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引用次数: 0

摘要

这本书收集了一些小故事，描述了作者课题组围绕肟化学发现的新反应。这些反应包括从离子转化（包括还原为未取代的亚胺和形成  - 亲电体）到亚胺基的生成和捕获，再到炔烃的一般合成。本文简要讨论了这些发现背后的机理推论和偶然的观察结果。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Chemical Adventures with Oximes

This account is a collection of vignettes describing new reactions discovered in the author ’ s group revolving around the chemistry of oximes. They range from ionic transformations, including reduction to unsubstituted imines and the formation of  -electrophiles, to the generation and capture of iminyl radicals, to a general synthesis of alkynes. The mechanistic reasonings and occasional serendipitous observations underlying these discoveries are discussed briefly

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来源期刊

Arkivoc 化学-有机化学

CiteScore

1.10

自引率

11.10%

发文量

120

审稿时长

3.1 months

期刊介绍： Arkivoc publishes full papers (not accounts) describing sound original work that is of interest to organic chemists (in areas of synthetic organic chemistry, bio-organic, organometallic, theoretical, and physical organic chemistry: General Papers describing sound original work Reviews and Accounts of selected topics Honorary Issues - Pay tribute to distinguished organic chemists (invited contributions) Thematic Issues - Cover important current topics in organic chemistry Regional Issues - Recognize organic chemistry in various countries.