稳定可膨胀硅酸铝悬浮液

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL Colloid Journal Pub Date : 2024-01-26 DOI:10.1134/s1061933x2360094x
K. A. Ovchinnikov, E. V. Podlesnova, F. E. Safarov, A. T. Akhmetov, A. V. Fakhreeva, E. I. Gusarova, N. A. Sergeeva, A.G. Telin
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引用次数: 0

摘要

摘要 本研究的目标是提高水膨胀硅酸铝分散体管道水力运输的能效。我们使用了一种商业悬浮液模型(其填料是一种复杂的铝硅酸盐混合物)来开发一种方法,从而有可能改善这种悬浮液的技术特性。悬浮液的改良包括添加有机和无机分散相颗粒膨胀抑制剂以及非离子表面活性剂。在添加剂的影响下,异质体系的屈服应力降低,沉降稳定性提高。研究表明,使用复合改性添加剂可以防止模型悬浮液的颗粒团聚,并使其在高达 70°C 的温度下具有沉降稳定性,这对于悬浮液的使用技术过程非常重要。从技术上讲,这项研究具有应用性质。我们采用了一种众所周知的方法来改良悬浮液,即防止分散相颗粒聚集并阻止它们与分散介质之间的离子交换。通过流变剪切和振荡试验,以及对悬浮液在各种改性添加剂作用下的沉降稳定性的研究,对悬浮液的成分进行了优化。这项工作的实际成果是成功实现了悬浮液的水力传输,其中分散相的含量比未改性悬浮液高出 50%,从而提高了工艺的能效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Stabilization of Swellable Aluminosilicate Suspensions

Abstract

The goal of this study is to increase the energy efficiency of pipeline hydraulic transport of water-swellable aluminosilicate dispersions. A model commercial suspension, the filler of which is a complex mixture of aluminosilicates, has been used to develop an approach that makes it possible to improve the technological properties of such suspensions. Modification of the suspensions consists in adding organic and inorganic inhibitors of swelling of dispersed phase particles, as well as nonionic surfactants. The influence of the additives leads to a decrease in the yield stress and an increase in sedimentation stability of the heterogeneous systems. It has been shown that the use of the complex modifying additive prevents the particles of the model suspension from agglomeration and provides it with sedimentation stability at temperatures up to 70°C, which is important for the technical process in which the suspension is intended to be used. Technically, the research is of an applied nature. A well-known approach to modifying suspensions is used, which consists in combating the aggregation of dispersed phase particles and blocking ion exchange between them and the dispersion medium. The performed set of rheological shear and oscillation tests and the study of the sedimentation stability of the suspensions in the presence of various modifying additives have resulted in optimizing their composition. The practical result of the work is the successful hydrotransport of the suspension in which the content of the dispersed phase is 50% higher than that in the unmodified suspension, thus increasing the energy efficiency of the process.

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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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