{"title":"利用超高效液相色谱-串联质谱法分析 Cladia aggregata (SW) Nyl 的去苷类化合物、二苯并呋喃类化合物和糖类衍生物的结构。","authors":"Priyanka Rawat, Sajan Lal Shyaula, Yatendra Singh, Sanjeev Kanojiya","doi":"10.1177/14690667241229910","DOIUrl":null,"url":null,"abstract":"<p><p><i>Cladia aggregate</i> (SW) Nyl is a lichenized fungi in the family Cladoniaceae producing characteristic secondary metabolites of interest. There are only limited chemical studies relating to the genus <i>Cladia.</i> A chemical study of the lichen <i>C. aggregata</i> was conducted and their chemical constituents were elucidated by ultra-performance liquid chromatography-electrospray ionization/triple-quadrupole tandem-mass spectrometry analysis. It is the first time report of structure analysis of its metabolite by liquid chromatography-mass spectrometry/mass spectrometry. The molecular masses for 20 compounds were detected from different fractions. Seven compounds were elucidated with mass spectrometry/mass spectrometry fragmentation pattern analysis. Barbatic acid (<b>12</b>) was identified as the major compound being common to all fractions. The identified compounds belong to depsides (<b>2</b>, <b>11</b>, <b>12</b> and <b>20</b>), dibenzofurans (<b>13</b>, <b>18</b>) and sugar derivatives (<b>1</b>) which are usually distributed in lichens.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":" ","pages":"116-124"},"PeriodicalIF":1.1000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structure analysis of depsides, dibenzofuran and sugar derivatives from <i>Cladia aggregata</i> (SW) Nyl using ultra-performance liquid chromatography-tandem mass spectrometry.\",\"authors\":\"Priyanka Rawat, Sajan Lal Shyaula, Yatendra Singh, Sanjeev Kanojiya\",\"doi\":\"10.1177/14690667241229910\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p><i>Cladia aggregate</i> (SW) Nyl is a lichenized fungi in the family Cladoniaceae producing characteristic secondary metabolites of interest. There are only limited chemical studies relating to the genus <i>Cladia.</i> A chemical study of the lichen <i>C. aggregata</i> was conducted and their chemical constituents were elucidated by ultra-performance liquid chromatography-electrospray ionization/triple-quadrupole tandem-mass spectrometry analysis. It is the first time report of structure analysis of its metabolite by liquid chromatography-mass spectrometry/mass spectrometry. The molecular masses for 20 compounds were detected from different fractions. Seven compounds were elucidated with mass spectrometry/mass spectrometry fragmentation pattern analysis. Barbatic acid (<b>12</b>) was identified as the major compound being common to all fractions. The identified compounds belong to depsides (<b>2</b>, <b>11</b>, <b>12</b> and <b>20</b>), dibenzofurans (<b>13</b>, <b>18</b>) and sugar derivatives (<b>1</b>) which are usually distributed in lichens.</p>\",\"PeriodicalId\":12007,\"journal\":{\"name\":\"European Journal of Mass Spectrometry\",\"volume\":\" \",\"pages\":\"116-124\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Mass Spectrometry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1177/14690667241229910\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/2/6 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Mass Spectrometry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/14690667241229910","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/2/6 0:00:00","PubModel":"Epub","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Structure analysis of depsides, dibenzofuran and sugar derivatives from Cladia aggregata (SW) Nyl using ultra-performance liquid chromatography-tandem mass spectrometry.
Cladia aggregate (SW) Nyl is a lichenized fungi in the family Cladoniaceae producing characteristic secondary metabolites of interest. There are only limited chemical studies relating to the genus Cladia. A chemical study of the lichen C. aggregata was conducted and their chemical constituents were elucidated by ultra-performance liquid chromatography-electrospray ionization/triple-quadrupole tandem-mass spectrometry analysis. It is the first time report of structure analysis of its metabolite by liquid chromatography-mass spectrometry/mass spectrometry. The molecular masses for 20 compounds were detected from different fractions. Seven compounds were elucidated with mass spectrometry/mass spectrometry fragmentation pattern analysis. Barbatic acid (12) was identified as the major compound being common to all fractions. The identified compounds belong to depsides (2, 11, 12 and 20), dibenzofurans (13, 18) and sugar derivatives (1) which are usually distributed in lichens.
期刊介绍：
JMS - European Journal of Mass Spectrometry, is a peer-reviewed journal, devoted to the publication of innovative research in mass spectrometry. Articles in the journal come from proteomics, metabolomics, petroleomics and other areas developing under the umbrella of the “omic revolution”.
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