热改性透平碳对其分形结构的影响

V. Mandzyuk, R. Lisovskiy, Yu.O. Kulyk, B. Rachiy, R.V. Solomovskyi
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引用次数: 0

摘要

利用低温测孔法研究了在不同条件下通过热改性获得的多孔碳材料(PCMs)的分形结构。结果表明,在改性温度为 300 和 600°C 时,形成的材料具有发达的微孔结构,其表面分形维数为 2.6。在改性温度为 400 和 500°C 时,表面分形维度值降至 2.22,这表明由于材料颗粒近表面层碳原子的大量清除,形成了几乎光滑的表面,微孔数量减少并过渡到中孔,小碳团聚成大碳团聚,形成了无孔碳材料微粒。
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The effect of thermal modification of turbostratic carbon on its fractal structure
Fractal structure of porous carbon materials (PCMs) obtained by thermal modification under different regimes was investigated using the method of low-temperature porometry. It was established that at modification temperatures of 300 and 600°C, materials with a developed microporous structure are formed, the surface fractal dimension of which is 2.6. At modification temperatures of 400 and 500°C, the value of the fractal dimension of the surface decreases to a value of 2.22, which indicates the formation of an almost smooth surface due to the intensive removal of carbon atoms from the near-surface layers of the material particles, a decrease in the number of micropores with their transition into mesopores, unification of small carbon clusters into larger ones and the formation of microparticles of non-porous carbon material.
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