立体化学 150 年--实例精选

IF 2.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Structural Chemistry Pub Date : 2024-02-22 DOI:10.1007/s11224-023-02276-z

Balazs Hargittai, Istvan Hargittai

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引用次数: 0

摘要

1874 年被认为是立体化学的诞生之年，这一年首次引入了化学中描述和讨论结构的第三个维度。立体化学和结构化学密切相关，但两者并非同义词。结构化学更强调计量方面，而立体化学更强调形状、对称性和手性。我们将回顾立体化学早期发展的一些节点。

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150 years of stereochemistry—selected examples

The year 1874 is considered to be the birth of stereochemistry when the third dimension in describing and discussing structures in chemistry was first introduced. Stereochemistry and structural chemistry are closely related though they are not each other’s synonyms. Structural chemistry implies greater emphasis on metrical aspects and stereochemistry on shape, symmetry, and chirality. We review some of the nodal points in the early development of stereochemistry.

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来源期刊

Structural Chemistry 化学-化学综合

CiteScore

3.80

自引率

11.80%

发文量

227

审稿时长

3.7 months

期刊介绍： Structural Chemistry is an international forum for the publication of peer-reviewed original research papers that cover the condensed and gaseous states of matter and involve numerous techniques for the determination of structure and energetics, their results, and the conclusions derived from these studies. The journal overcomes the unnatural separation in the current literature among the areas of structure determination, energetics, and applications, as well as builds a bridge to other chemical disciplines. Ist comprehensive coverage encompasses broad discussion of results, observation of relationships among various properties, and the description and application of structure and energy information in all domains of chemistry. We welcome the broadest range of accounts of research in structural chemistry involving the discussion of methodologies and structures,experimental, theoretical, and computational, and their combinations. We encourage discussions of structural information collected for their chemicaland biological significance.