源自邻苯二酚支架双(N,N-二乙基硫脲)的金(I) {2}-金属硼酸盐:合成与结构

Chien Thang Pham, Hung Huy Nguyen, Ulrich Abram, Thu Thuy Pham
{"title":"源自邻苯二酚支架双(N,N-二乙基硫脲)的金(I) {2}-金属硼酸盐:合成与结构","authors":"Chien Thang Pham, Hung Huy Nguyen, Ulrich Abram, Thu Thuy Pham","doi":"10.1002/zaac.202400012","DOIUrl":null,"url":null,"abstract":"One‐pot reactions of a catechol‐scaffolding aroylbis(N,N‐diethylthiourea) H2Lcat and mixtures of lanthanide nitrates Ln(NO3)3 (Ln3+ = La3+, Nd3+ or Yb3+) or indium(III) chloride InCl3 and [Au(tht)Cl] in methanol in the presence of the supporting base Et3N result in gold(I) {2}‐metallacoronates. Depending on radii of the trivalent metal ions, the corresponding complexes are separated either in the neutral form with the composition {(NO3‐κ2‐O,O’)Ln [[EQUATION]] [Au2(Lcat)2]} in the cases of La3+ and Nd3+ or as the ‘ion‐pair’ {Yb [[EQUATION]] [Au2(Lcat)2]}+(NO3)‐ for the Yb(III) compound. The cationic complexes can be isolated in higher yields as the PF6‐ salts {M [[EQUATION]] [Au2(Lcat)2]}+(PF6)‐ (M3+ = Yb3+ or In3+) by treatment of reaction mixtures with (n‐Bu4N)(PF6).","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"31 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gold(I) {2}‐Metallacoronates derived from a Catechol‐scaffolding Aroylbis(N,N‐diethylthiourea): Syntheses and Structures\",\"authors\":\"Chien Thang Pham, Hung Huy Nguyen, Ulrich Abram, Thu Thuy Pham\",\"doi\":\"10.1002/zaac.202400012\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"One‐pot reactions of a catechol‐scaffolding aroylbis(N,N‐diethylthiourea) H2Lcat and mixtures of lanthanide nitrates Ln(NO3)3 (Ln3+ = La3+, Nd3+ or Yb3+) or indium(III) chloride InCl3 and [Au(tht)Cl] in methanol in the presence of the supporting base Et3N result in gold(I) {2}‐metallacoronates. Depending on radii of the trivalent metal ions, the corresponding complexes are separated either in the neutral form with the composition {(NO3‐κ2‐O,O’)Ln [[EQUATION]] [Au2(Lcat)2]} in the cases of La3+ and Nd3+ or as the ‘ion‐pair’ {Yb [[EQUATION]] [Au2(Lcat)2]}+(NO3)‐ for the Yb(III) compound. The cationic complexes can be isolated in higher yields as the PF6‐ salts {M [[EQUATION]] [Au2(Lcat)2]}+(PF6)‐ (M3+ = Yb3+ or In3+) by treatment of reaction mixtures with (n‐Bu4N)(PF6).\",\"PeriodicalId\":23934,\"journal\":{\"name\":\"Zeitschrift für anorganische und allgemeine Chemie\",\"volume\":\"31 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-02-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für anorganische und allgemeine Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/zaac.202400012\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400012","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

在支持碱 Et3N 的存在下,儿茶酚-支架酰基双(N,N-二乙基硫脲)H2Lcat 与镧系元素硝酸盐 Ln(NO3)3 (Ln3+ = La3+、Nd3+ 或 Yb3+)或氯化铟(III)InCl3 和[Au(tht)Cl]的混合物在甲醇中发生单锅反应,生成金(I){2}-金属硼酸盐。根据三价金属离子的半径,相应的配合物以中性形式分离,其组成为{(NO3-κ2-O,O')Ln[[公式]]。[Au2(Lcat)2]}(La3+ 和 Nd3+),或者以 "离子对"{Yb [[EQUATION]] 的形式分离。[Au2(Lcat)2]}+(NO3)-来表示镱(III)化合物。阳离子配合物可以作为 PF6- 盐{M [[EQUATION]] 分离出来,产量更高。[Au2(Lcat)2]}+(PF6)-(M3+ = Yb3+ 或 In3+)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Gold(I) {2}‐Metallacoronates derived from a Catechol‐scaffolding Aroylbis(N,N‐diethylthiourea): Syntheses and Structures
One‐pot reactions of a catechol‐scaffolding aroylbis(N,N‐diethylthiourea) H2Lcat and mixtures of lanthanide nitrates Ln(NO3)3 (Ln3+ = La3+, Nd3+ or Yb3+) or indium(III) chloride InCl3 and [Au(tht)Cl] in methanol in the presence of the supporting base Et3N result in gold(I) {2}‐metallacoronates. Depending on radii of the trivalent metal ions, the corresponding complexes are separated either in the neutral form with the composition {(NO3‐κ2‐O,O’)Ln [[EQUATION]] [Au2(Lcat)2]} in the cases of La3+ and Nd3+ or as the ‘ion‐pair’ {Yb [[EQUATION]] [Au2(Lcat)2]}+(NO3)‐ for the Yb(III) compound. The cationic complexes can be isolated in higher yields as the PF6‐ salts {M [[EQUATION]] [Au2(Lcat)2]}+(PF6)‐ (M3+ = Yb3+ or In3+) by treatment of reaction mixtures with (n‐Bu4N)(PF6).
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Oxygen redox activity in battery cathodes and the role of underbonded oxygen High‐Pressure Synthesis and Crystal Structure of the Inoborate Ni[B2O2(OH)4] Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3− Chiral Homodinuclear Dysprosium Macrocyclic Complexes with Single‐molecule Magnetic Behaviours From tin(II) to tin(IV): Following solid‐liquid reactions by microscopy
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1