Aqua-bis-(2,2'-bi-pyridine-κ2N,N')(isonicotinamide-κN)ruthenium(II) bis-(trifluoromethanesulfonate).

IUCrData Pub Date : 2024-02-01 DOI:10.1107/S2414314624001147

Liam Faubert , Hadi D. Arman , Rafael A. Adrian , M. Bolte (Editor)

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引用次数: 0

摘要

在标题复合物[Ru(C10H8N2)2(C6H6N2O)(H2O)](CF3SO3)2 中，中心 RuII 原子由两个双齿 2,2'-双吡啶、一个等效烟酰胺配体和一个水分子单元在畸变的八面体环境中配位成六面体，三氟甲烷磺酸离子完成了复合物的外配位层。水分子单元中的氢键和相邻分子单元中吡啶环之间微弱的π-π堆叠相互作用使复合物排列成平行于 c 轴的柱状。

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Aquabis(2,2′-bipyridine-κ2 N,N′)(isonicotinamide-κN)ruthenium(II) bis(trifluoromethanesulfonate)

In the crystal structure of the title compound, the ruthenium(II) metal center is surrounded by two bidentate 2,2′-bipyridine, an isonicotinamide ligand, and a water in a distorted octahedral geometry. Hydrogen bonding is present between counter-ion and ligand.

In the title complex, [Ru(C₁₀H₈N₂)₂(C₆H₆N₂O)(H₂O)](CF₃SO₃)₂, the central Ru^II atom is sixfold coordinated by two bidentate 2,2′-bipyridine, an isonicotinamide ligand, and a water molecule in a distorted octahedral environment with trifluoromethanesulfonate ions completing the outer coordination sphere of the complex. Hydrogen bonding involving the water molecule and weak π–π stacking interactions between the pyridyl rings in adjacent molecules contribute to the alignment of the complexes in columns parallel to the c axis.

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