Esther H. Park , Sarah M. Ortiz , Todd K. Liang , Bradley W. Smucker , S. Bernès (Editor)
{"title":"顺式，顺式，顺式-二氯双(N 4,N 4-二甲基吡啶-4-胺-κN 1)双(二甲基亚砜-κS)钌(II)","authors":"Esther H. Park , Sarah M. Ortiz , Todd K. Liang , Bradley W. Smucker , S. Bernès (Editor)","doi":"10.1107/S2414314624001913","DOIUrl":null,"url":null,"abstract":"<div><p>In the structure of the title compound, the Ru—N distances of the DMAP ligands are influenced by the <em>trans</em> chloride or dimethylsulfoxide-κ<em>S</em> ligands.</p></div><div><p>The structure of the title compound, [RuCl<sub>2</sub>(C<sub>7</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>(C<sub>2</sub>H<sub>6</sub>OS)<sub>2</sub>], has monoclinic (<em>P</em>2<sub>1</sub>/<em>n</em>) symmetry. The Ru—N distances of the coordination compound are influenced by the <em>trans</em> chloride or dimethylsulfoxide-κ<em>S</em> ligands. The molecular structure exhibits disorder for two of the terminal methyl groups of a dimethyl sulfoxide ligand. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (270KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"cis,cis,cis-Dichloridobis(N 4,N 4-dimethylpyridin-4-amine-κN 1)bis(dimethyl sulfoxide-κS)ruthenium(II)\",\"authors\":\"Esther H. Park , Sarah M. Ortiz , Todd K. Liang , Bradley W. Smucker , S. Bernès (Editor)\",\"doi\":\"10.1107/S2414314624001913\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the structure of the title compound, the Ru—N distances of the DMAP ligands are influenced by the <em>trans</em> chloride or dimethylsulfoxide-κ<em>S</em> ligands.</p></div><div><p>The structure of the title compound, [RuCl<sub>2</sub>(C<sub>7</sub>H<sub>10</sub>N<sub>2</sub>)<sub>2</sub>(C<sub>2</sub>H<sub>6</sub>OS)<sub>2</sub>], has monoclinic (<em>P</em>2<sub>1</sub>/<em>n</em>) symmetry. The Ru—N distances of the coordination compound are influenced by the <em>trans</em> chloride or dimethylsulfoxide-κ<em>S</em> ligands. The molecular structure exhibits disorder for two of the terminal methyl groups of a dimethyl sulfoxide ligand. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (270KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 3\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000087\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000087","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
In the structure of the title compound, the Ru—N distances of the DMAP ligands are influenced by the trans chloride or dimethylsulfoxide-κS ligands.
The structure of the title compound, [RuCl2(C7H10N2)2(C2H6OS)2], has monoclinic (P21/n) symmetry. The Ru—N distances of the coordination compound are influenced by the trans chloride or dimethylsulfoxide-κS ligands. The molecular structure exhibits disorder for two of the terminal methyl groups of a dimethyl sulfoxide ligand.
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