Thermodynamic modeling of the Ti–Al–V system over the entire composition and a wide temperature range

Ti–Al–V alloys have received considerable attention owing to their excellent high-temperature mechanical properties. After conducting a critical review of the available experimental data for the ternary Ti–Al–V system, a thermodynamic assessment of the system was carried out over the entire composition and a wide temperature range utilizing the CALPHAD method. The extensive homogeneity ranges of the ${\alpha }_2$ and $\gamma$ phases were satisfactorily reproduced. Of particular significance was the first accurate description of the phase equilibria at 1573 K. The model parameters obtained in this study well represented the thermochemical properties and phase equilibria of the experimental data. Furthermore, the enthalpies of the widely used Ti alloy Ti–6Al–4V were reproduced using the thermodynamic description established in this study. Thus, this study provides a reliable basis for guiding the development and design of Ti–Al–V alloys.