对氨基苯环丙基甲基甲基丙烯酸酯与甲基丙烯酸甲酯的 Radical 共聚作用

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED Russian Journal of Applied Chemistry Pub Date : 2024-03-12 DOI:10.1134/S1070427223050038
K. G. Guliyev, V. E. Vahabova
{"title":"对氨基苯环丙基甲基甲基丙烯酸酯与甲基丙烯酸甲酯的 Radical 共聚作用","authors":"K. G. Guliyev,&nbsp;V. E. Vahabova","doi":"10.1134/S1070427223050038","DOIUrl":null,"url":null,"abstract":"<p><i>p</i>-Aminophenylcyclopropylmethyl methacrylate monomer was prepared, and its free-radical copolymerization with methyl methacrylate was performed. The monomer and copolymer were characterized by IR and NMR spectroscopy. The relative activity constants of the monomer were determined, and the monomer activity and polarity were calculated by the Alfrey–Price method. The copolymerization constant of <i>p</i>-aminophenylcyclopropylmethyl methacrylate exceeds that of methyl methacrylate; therefore, the copolymer is enriched in units of specifically this comonomer. The copolymers based on <i>p-</i>aminophenylcyclopropylmethyl methacrylate exhibit high biological activity toward Gram-positive (<i>Staphylococcus aureus</i>) and Gram-negative (<i>Escherichia coli</i>) bacteria and toward <i>Candida albicans fungi</i>.</p>","PeriodicalId":757,"journal":{"name":"Russian Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Radical Copolymerization of p-Aminophenylcyclopropylmethyl Methacrylate with Methyl Methacrylate\",\"authors\":\"K. G. Guliyev,&nbsp;V. E. Vahabova\",\"doi\":\"10.1134/S1070427223050038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><i>p</i>-Aminophenylcyclopropylmethyl methacrylate monomer was prepared, and its free-radical copolymerization with methyl methacrylate was performed. The monomer and copolymer were characterized by IR and NMR spectroscopy. The relative activity constants of the monomer were determined, and the monomer activity and polarity were calculated by the Alfrey–Price method. The copolymerization constant of <i>p</i>-aminophenylcyclopropylmethyl methacrylate exceeds that of methyl methacrylate; therefore, the copolymer is enriched in units of specifically this comonomer. The copolymers based on <i>p-</i>aminophenylcyclopropylmethyl methacrylate exhibit high biological activity toward Gram-positive (<i>Staphylococcus aureus</i>) and Gram-negative (<i>Escherichia coli</i>) bacteria and toward <i>Candida albicans fungi</i>.</p>\",\"PeriodicalId\":757,\"journal\":{\"name\":\"Russian Journal of Applied Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-03-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Applied Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070427223050038\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070427223050038","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0

摘要

摘要p-氨基苯基环丙基甲基甲基丙烯酸酯单体的制备及其与甲基丙烯酸甲酯的自由基共聚。通过红外光谱和核磁共振光谱对单体和共聚物进行了表征。测定了单体的相对活性常数,并用 Alfrey-Price 法计算了单体活性和极性。对氨基苯基环丙基甲基甲基丙烯酸酯的共聚常数超过了甲基丙烯酸甲酯的共聚常数,因此共聚物中富含这种单体的单元。基于对氨苯基环丙基甲基甲基丙烯酸酯的共聚物对革兰氏阳性(金黄色葡萄球菌)和革兰氏阴性(大肠杆菌)细菌以及白色念珠菌真菌具有很高的生物活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Radical Copolymerization of p-Aminophenylcyclopropylmethyl Methacrylate with Methyl Methacrylate

p-Aminophenylcyclopropylmethyl methacrylate monomer was prepared, and its free-radical copolymerization with methyl methacrylate was performed. The monomer and copolymer were characterized by IR and NMR spectroscopy. The relative activity constants of the monomer were determined, and the monomer activity and polarity were calculated by the Alfrey–Price method. The copolymerization constant of p-aminophenylcyclopropylmethyl methacrylate exceeds that of methyl methacrylate; therefore, the copolymer is enriched in units of specifically this comonomer. The copolymers based on p-aminophenylcyclopropylmethyl methacrylate exhibit high biological activity toward Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria and toward Candida albicans fungi.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
期刊最新文献
Sorption of Gases in Additive Polynorbornene with Norbornyl Substituents Pyrolysis of Polyethylene Terephthalate: Process Features and Composition of Reaction Products Electrochemical Deposition of Iridium onto Gallium Arsenide from a Sulfamate Electrolyte Based on Hexachloroiridic(IV) Acid CrOx–SiO2 Catalysts in Nonoxidative Propane Dehydrogenation: Effect of Adding Cerium Dioxide Hydrogen Decrepitation of NdFeB End-of-Life Magnets with the Preliminary Three-Step Surface Cleaning
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1