{"title":"含 17 元大环分子的锌(II)酞菁的合成与表征，作为从水溶液中去除 Ag(I) 的新型萃取剂","authors":"Yasemin Baygu Yıldız","doi":"10.1007/s11243-024-00577-8","DOIUrl":null,"url":null,"abstract":"<div><p>A new aza-thia macrocycle compound was obtained with high dilution reaction. A new zinc(II) phthalocyanine containing four 17-membered macrocycle moieties with nitrogen-sulfur donor atoms was synthesized in a multi-step reaction sequence. Zn(II) phthalocyanine (<b>S</b><sub><b>4</b></sub><b>N-ZnPc)</b> and all of the new compounds were characterized by elemental analysis and different spectroscopic methods such as <sup>1</sup>H NMR, <sup>13</sup>C NMR, IR, UV–vis and mass. Obtained macrocyclic compounds <b>6</b> and <b>S</b><sub><b>4</b></sub><b>N-ZnPc</b> were used in solvent extraction of metals such as Ag<sup>+</sup>, Hg<sup>2+</sup>, Cd<sup>2+</sup>, Zn<sup>2+</sup>, Cu<sup>2+</sup>, Ni<sup>2+</sup>, Pb<sup>2+</sup> and Cr<sup>3+</sup> from aqueous phase to the organic phase. The results of two-phase extraction studies on new macrocyclic compounds showed very high selectivity for silver ions compared to other metal cations.</p></div>","PeriodicalId":803,"journal":{"name":"Transition Metal Chemistry","volume":"49 4","pages":"237 - 244"},"PeriodicalIF":1.6000,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and characterization of zinc(II) phthalocyanine containing 17-membered macrocyclic moiety as new extractant for the removal of Ag(I) from aqueous solution\",\"authors\":\"Yasemin Baygu Yıldız\",\"doi\":\"10.1007/s11243-024-00577-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new aza-thia macrocycle compound was obtained with high dilution reaction. A new zinc(II) phthalocyanine containing four 17-membered macrocycle moieties with nitrogen-sulfur donor atoms was synthesized in a multi-step reaction sequence. Zn(II) phthalocyanine (<b>S</b><sub><b>4</b></sub><b>N-ZnPc)</b> and all of the new compounds were characterized by elemental analysis and different spectroscopic methods such as <sup>1</sup>H NMR, <sup>13</sup>C NMR, IR, UV–vis and mass. Obtained macrocyclic compounds <b>6</b> and <b>S</b><sub><b>4</b></sub><b>N-ZnPc</b> were used in solvent extraction of metals such as Ag<sup>+</sup>, Hg<sup>2+</sup>, Cd<sup>2+</sup>, Zn<sup>2+</sup>, Cu<sup>2+</sup>, Ni<sup>2+</sup>, Pb<sup>2+</sup> and Cr<sup>3+</sup> from aqueous phase to the organic phase. The results of two-phase extraction studies on new macrocyclic compounds showed very high selectivity for silver ions compared to other metal cations.</p></div>\",\"PeriodicalId\":803,\"journal\":{\"name\":\"Transition Metal Chemistry\",\"volume\":\"49 4\",\"pages\":\"237 - 244\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-03-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transition Metal Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11243-024-00577-8\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transition Metal Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11243-024-00577-8","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis and characterization of zinc(II) phthalocyanine containing 17-membered macrocyclic moiety as new extractant for the removal of Ag(I) from aqueous solution
A new aza-thia macrocycle compound was obtained with high dilution reaction. A new zinc(II) phthalocyanine containing four 17-membered macrocycle moieties with nitrogen-sulfur donor atoms was synthesized in a multi-step reaction sequence. Zn(II) phthalocyanine (S4N-ZnPc) and all of the new compounds were characterized by elemental analysis and different spectroscopic methods such as 1H NMR, 13C NMR, IR, UV–vis and mass. Obtained macrocyclic compounds 6 and S4N-ZnPc were used in solvent extraction of metals such as Ag+, Hg2+, Cd2+, Zn2+, Cu2+, Ni2+, Pb2+ and Cr3+ from aqueous phase to the organic phase. The results of two-phase extraction studies on new macrocyclic compounds showed very high selectivity for silver ions compared to other metal cations.
期刊介绍：
Transition Metal Chemistry is an international journal designed to deal with all aspects of the subject embodied in the title: the preparation of transition metal-based molecular compounds of all kinds (including complexes of the Group 12 elements), their structural, physical, kinetic, catalytic and biological properties, their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems etc.
Manuscripts submitted to the journal should be of broad appeal to the readership and for this reason, papers which are confined to more specialised studies such as the measurement of solution phase equilibria or thermal decomposition studies, or papers which include extensive material on f-block elements, or papers dealing with non-molecular materials, will not normally be considered for publication. Work describing new ligands or coordination geometries must provide sufficient evidence for the confident assignment of structural formulae; this will usually take the form of one or more X-ray crystal structures.
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