均场非谐波量子玻璃中的两级系统和谐波激发

Thibaud Maimbourg
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摘要

结构玻璃在低温下显示出一系列热力学观测指标的反常现象。最突出的例子是比热在温度下的线性缩放,这与晶体中发现的德拜立方缩放不同,是由声子引起的。无定形固体中的这种比热过剩被认为是由被称为隧道两级系统(TTLS)的现象学软激发引起的。从第一原理的角度来看,它们的性质及其统计特性仍然难以捉摸。在这项工作中,我们研究了 KHGPS 模型的典型量化版本--耦合非谐振子的均场玻璃模型--的整个相图,重点是比热。热力学是通过非经典扩展求解的。我们的研究表明,在该模型的复制对称区域,直到复制对称性被持续打破的边缘玻璃转变线,德拜近似的无序版本是成立的:比热由谐振激振主导,在转变过程中诱发幂律缩放,由随机矩阵理论支配。这一机制概括了之前文献中的半经典论证。我们研究了边缘玻璃相,由于瞬子的出现,半经典扩展变得非微扰,从而克服了无序Debye行为。在玻璃相内部,瞬子方法的可变解提供了作为 TTLS 的主要激元,它们会产生线性特定热。因此,这一阶段包含了 TTLS 和由相互作用产生的谐波激振的混合。最后,我们建议通过与自旋玻色子模型的类比来超越变分近似。
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Two-level systems and harmonic excitations in a mean-field anharmonic quantum glass
Structural glasses display at low temperature a set of anomalies in thermodynamic observables. The prominent example is the linear-in-temperature scaling of the specific heat, at odds with the Debye cubic scaling found in crystals, due to acoustic phonons. Such an excess of specific heat in amorphous solids is thought of arising from phenomenological soft excitations dubbed tunneling two-level systems (TTLS). Their nature as well as their statistical properties remain elusive from a first-principle viewpoint. In this work we investigate the canonically quantized version of the KHGPS model, a mean-field glass model of coupled anharmonic oscillators, across its phase diagram, with an emphasis on the specific heat. The thermodynamics is solved in a semiclassical expansion. We show that in the replica-symmetric region of the model, up to the marginal glass transition line where replica symmetry gets continuously broken, a disordered version of the Debye approximation holds: the specific heat is dominated by harmonic vibrational excitations inducing a power-law scaling at the transition, ruled by random matrix theory. This mechanism generalizes a previous semiclassical argument in the literature. We then study the marginal glass phase where the semiclassical expansion becomes non-perturbative due to the emergence of instantons that overcome disordered Debye behavior. Inside the glass phase, a variational solution to the instanton approach provides the prevailing excitations as TTLS, which generate a linear specific heat. This phase thus hosts a mix of TTLS and harmonic excitations generated by interactions. We finally suggest to go beyond the variational approximation through an analogy with the spin-boson model.
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