利用电阻率法对盐碱土的解冻行为进行实验研究

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-21 DOI:10.1093/jge/gxae037
Cihai Chen, Zhilong Yang, Yaping Deng, Haichun Ma, Jiazhong Qian
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引用次数: 0

摘要

电阻率法已被广泛用于研究冻土和监测冻融过程。然而,人们对解冻过程中的电反应机制还缺乏透彻的了解。在本研究中,我们考虑了土壤类型和盐度的影响,研究了盐碱土在温度范围 ∼-10 至 15 ° C 的解冻行为。在三种土壤类型(硅砂、砂土和淤泥)和三种盐度(0.01 S/m、0.1 S/m 和 1 S/m)下共进行了九次实验。结果表明,电阻率随温度的变化可分为三个阶段。在第Ⅰ阶段,迂回度和不冻水含量对电阻率的下降起主要作用。在第Ⅱ阶段,即等温或接近等温的过程中,由于残冰解冻和孔隙水运动,电阻率仍会略有下降。在第Ⅲ阶段,离子迁移率对电阻率的下降有重要影响。此外,等温过程只发生在硅砂中,这可以用潜热效应来解释。温度与电阻率之间的指数模型和线性模型被用来拟合第一阶段和第三阶段的实验数据。不同模型的拟合参数与土壤类型和盐度有很大关系。此外,还估算了 0 °C 以下的不冻水含量,并分析了估算的不确定性。
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Experimental investigation of thawing behavior of saline soils using resistivity method
Electrical resistivity method has been widely used to study permafrost and to monitor the process of freezing-thawing. However, a thorough understanding of the mechanism of electrical response during thawing is missing. In this study, we investigated the thawing behavior of saline soils in the temperature range ∼-10 to 15 °C considering the effects of soil type and salinity. A total of nine experiments were performed with three soil types (silica sand, sandy soil and silt) and three salinities (0.01 S/m, 0.1 S/m and 1 S/m). The results show that resistivity variations with temperature can be divided into three stages. In Stage I, tortuosity and unfrozen water content play major roles in the decrease of resistivity. In Stage Ⅱ, which is an isothermal or near isothermal process, resistivity still decreases slightly due to the thawing of residual ice and pore water movement. In Stage III, ionic mobility plays an important impact on decreasing resistivity. In addition, the isothermal process is found to only occur in silica sand which can be explained by latent heat effect. Exponential and linear models linking temperature with resistivity are used to fit the experimental data in Stage I and Stage III. The fitting parameter in different models shows great correlation with soil type and salinity. Furthermore, unfrozen water content below 0 °C is also estimated and uncertainty of estimation is analyzed.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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