将甘蔗渣转化为沸石材料:一种可持续的废水处理方法

Nuhu A A, Garba Zn, H. Ibrahim, S. Abdulrazak
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摘要

甘蔗渣是一种富含硅酸盐和纤维素的农副产品,但仍未得到充分利用,在全球固体废物日益增长的困境中扮演着重要角色。本研究深入探讨了通过水热处理从经济上可行的甘蔗渣中提炼出沸石材料并对其进行改良的复杂过程。通过采用 24 全因子设计优化合成条件,该研究细致地探讨了四个关键工艺变量:粒度(90-200 微米)、试剂(0.5 M NaOH+1.5 M NaCl)比例(0.5-1)、接触时间(40-72 小时)和温度(70-100 摄氏度)。研究仔细划分了这些变量对沸石孔隙率的细微影响。经过 16 次实验后,研究确定的最佳合成条件如下:粒度为 90 微米,试剂比例为 1,接触时间为 72 小时,温度为 100 摄氏度。表明所开发模型适当性和显著性的拟合统计量为:R² = 0.9965,调整 R² = 0.9827,预测 R² = 0.9018;Adeq 精确度 = 26.6195;Std.Dev. = 1.69,C.V = 2.72%。此外,由于孔隙率增大,合成的沸石可能具有更强的吸附能力。这为废水处理开辟了前景广阔的途径,为无数环境问题提供了有效的解决方案。这种方法不仅解决了废物管理的紧迫问题,还强调了将废物转化为宝贵资源以促进可持续发展的潜力。
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Transforming sugarcane bagasse into zeolitic material: a sustainable approach to wastewater treatment
Sugarcane bagasse, an abundant agricultural byproduct rich in silicates and cellulose, continues to be underutilized, making a significant contribution to the ever-growing global solid waste predicament. This study delves into the intricate process of producing and enhancing zeolite material derived from economically viable sugarcane bagasse by employing hydrothermal treatment. It meticulously explores four pivotal process variables: particle size (90-200 µm), reagent (0.5 M NaOH+1.5 M NaCl) ratio (0.5-1), contact time (40-72 hr), and temperature (70-100oC), by utilizing 24 full factorial design to optimize synthesis conditions. The investigation carefully delineates the nuanced impacts of these variables on the resulting zeolite porosity. After 16 experimental runs, the study identified the optimal synthesis conditions as follows: a particle size of 90 µm, a reagent ratio of 1, a contact time of 72 hr, and a temperature of 100oC. The fit statistics that signified the adequacy and significance of the developed model are R² = 0.9965, Adjusted R² = 0.9827, Predicted R² = 0.9018; Adeq Precision = 26.6195; Std. Dev. = 1.69 and C.V = 2.72%. Furthermore, the synthesized zeolite exhibited potentially a heightened adsorption capability due to its amplified porosity. This opens up promising avenues for wastewater treatment, offering effective solutions to a myriad of environmental concerns. This approach not only addresses the pressing issue of waste management but also underscores the potential of transforming waste into valuable resources for sustainable development.  
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