{"title":"金催化分子间赫克反应的异常选择性","authors":"Mahesh Bhagwan Thoke, Nitin T. Patil","doi":"10.1007/s13404-024-00342-w","DOIUrl":null,"url":null,"abstract":"<p>The Heck reaction has been considered a robust method for the cross-coupling reaction of olefins and aryl halides to yield alkenes. However, the most significant requirement is the necessity of electronically biased olefins and the requirement of directing group to control the regioselectivity of the Heck reaction. The research group of Patil and Gandon recently documented the gold-catalyzed Heck reaction, demonstrating the utilization of simple aliphatic alkenes as substrates. This approach does not need electronically biased olefins and offers a distinct regioselectivity when compared to the Heck reaction catalyzed by other transition metal catalysts.</p>","PeriodicalId":581,"journal":{"name":"Gold Bulletin","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Unusual selectivity in gold-catalyzed intermolecular Heck reactions\",\"authors\":\"Mahesh Bhagwan Thoke, Nitin T. Patil\",\"doi\":\"10.1007/s13404-024-00342-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The Heck reaction has been considered a robust method for the cross-coupling reaction of olefins and aryl halides to yield alkenes. However, the most significant requirement is the necessity of electronically biased olefins and the requirement of directing group to control the regioselectivity of the Heck reaction. The research group of Patil and Gandon recently documented the gold-catalyzed Heck reaction, demonstrating the utilization of simple aliphatic alkenes as substrates. This approach does not need electronically biased olefins and offers a distinct regioselectivity when compared to the Heck reaction catalyzed by other transition metal catalysts.</p>\",\"PeriodicalId\":581,\"journal\":{\"name\":\"Gold Bulletin\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-03-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Gold Bulletin\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1007/s13404-024-00342-w\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Gold Bulletin","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s13404-024-00342-w","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Unusual selectivity in gold-catalyzed intermolecular Heck reactions
The Heck reaction has been considered a robust method for the cross-coupling reaction of olefins and aryl halides to yield alkenes. However, the most significant requirement is the necessity of electronically biased olefins and the requirement of directing group to control the regioselectivity of the Heck reaction. The research group of Patil and Gandon recently documented the gold-catalyzed Heck reaction, demonstrating the utilization of simple aliphatic alkenes as substrates. This approach does not need electronically biased olefins and offers a distinct regioselectivity when compared to the Heck reaction catalyzed by other transition metal catalysts.
期刊介绍：
Gold Bulletin is the premier international peer reviewed journal on the latest science, technology and applications of gold. It includes papers on the latest research advances, state-of-the-art reviews, conference reports, book reviews and highlights of patents and scientific literature. Gold Bulletin does not publish manuscripts covering the snthesis of Gold nanoparticles in the presence of plant extracts or other nature-derived extracts. Gold Bulletin has been published over 40 years as a multidisciplinary journal read by chemists, physicists, engineers, metallurgists, materials scientists, biotechnologists, surface scientists, and nanotechnologists amongst others, both within industry and academia. Gold Bulletin is published in Association with the World Gold Council.
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