2-羟基-1, 2-二苯基乙烷-1 的铬、铜配合物的合成与光谱分析

Mohd Amin Mir, Syed M. Hasnain, Samar D. Dernayka
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摘要

利用各种化学方法分析了铬(II)和铜(II)与安息香的络合物。对上述络合物进行了元素分析,并通过红外光谱、电子光谱和核磁共振光谱进行了表征。数据分析显示,金属离子形成的配体与金属比例为 1:1,代表 [Cr (B)] H2O 和 [Cu (B)] 2H2O 离子络合物,其中 B 代表安息香。根据红外光谱分析数据,螯合化学反应是通过安息香的羰基氧和羟基氧发生的。电子光谱数据分析和质子核磁共振光谱分析阐明了复合物的结构分析。与金属的复合物系统还显示出对多种细菌菌株的抗菌特性。
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Synthesis and Spectral Analysis of Chromium, Copper Complexes of 2-Hydroxy-1, 2-diphenylethan-1
Various chemical process have been utilized to analyze chromium (II) and copper (II) complexes with Benzoin. The fore mentioned complexes were analyzed for elemental analyses, and characterized by infrared, electronic spectra, NMR spectroscopy. The data analysis showed the metal ion formation of 1:1 ligand to metal ratio representing the [Cr (B)] H2O and [Cu (B)] 2H2O ionic complex in which B represents the Benzoin. According to the data analyzed by Infrared spectroscopy, it is through the carbonyl and hydroxyl oxygen’s of the Benzoin that chelation chemistry takes place. The complex structural analysis was elucidated by electronic spectral data analysis and by proton NMR spectroscopy. The complex systems with the metals also showed antimicrobial property against many bacterial strains.  
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