通过微结构工程合理设计金刚石:从合成到应用

IF 19.5 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Carbon Energy Pub Date : 2024-04-25 DOI:10.1002/cey2.570
Yalun Ku, Wentao Huang, Xing Li, Li Wan, Kuikui Zhang, Longbin Yan, Ying Guo, Shaobo Cheng, Chongxin Shan
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引用次数: 0

摘要

金刚石具有优异的热导率和可调带隙。目前,高压、高温和化学气相沉积法是商业规模生产合成金刚石最有前途的策略。尽管金刚石已被广泛应用于珠宝和切割/研磨工作中,但通过微结构工程实现其高端应用一直是人们追求的目标。在此,我们将讨论金刚石中出现的微观结构,并进一步集中讨论利用电子显微镜技术进行的前沿研究,以阐明石墨和金刚石在合成和器件制造过程中的转变机制。我们详细阐述了不同微观结构对金刚石电气应用的影响,尤其是光电、电气和热性能。此外,还总结了最近报道的通过原位显微镜技术揭示的弹性和塑性变形。最后,提出了局限性、前景和相应的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Rational design of diamond through microstructure engineering: From synthesis to applications

Diamond possesses excellent thermal conductivity and tunable bandgap. Currently, the high-pressure, high-temperature, and chemical vapor deposition methods are the most promising strategies for the commercial-scale production of synthetic diamond. Although diamond has been extensively employed in jewelry and cutting/grinding tasks, the realization of its high-end applications through microstructure engineering has long been sought. Herein, we discuss the microstructures encountered in diamond and further concentrate on cutting-edge investigations utilizing electron microscopy techniques to illuminate the transition mechanism between graphite and diamond during the synthesis and device constructions. The impacts of distinct microstructures on the electrical applications of diamond, especially the photoelectrical, electrical, and thermal properties, are elaborated. The recently reported elastic and plastic deformations revealed through in situ microscopy techniques are also summarized. Finally, the limitations, perspectives, and corresponding solutions are proposed.

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来源期刊
Carbon Energy
Carbon Energy Multiple-
CiteScore
25.70
自引率
10.70%
发文量
116
审稿时长
4 weeks
期刊介绍: Carbon Energy is an international journal that focuses on cutting-edge energy technology involving carbon utilization and carbon emission control. It provides a platform for researchers to communicate their findings and critical opinions and aims to bring together the communities of advanced material and energy. The journal covers a broad range of energy technologies, including energy storage, photocatalysis, electrocatalysis, photoelectrocatalysis, and thermocatalysis. It covers all forms of energy, from conventional electric and thermal energy to those that catalyze chemical and biological transformations. Additionally, Carbon Energy promotes new technologies for controlling carbon emissions and the green production of carbon materials. The journal welcomes innovative interdisciplinary research with wide impact. It is indexed in various databases, including Advanced Technologies & Aerospace Collection/Database, Biological Science Collection/Database, CAS, DOAJ, Environmental Science Collection/Database, Web of Science and Technology Collection.
期刊最新文献
Issue Information Cover Image, Volume 6, Number 10, October 2024 Back Cover Image, Volume 6, Number 10, October 2024 Interface and doping engineering of V2C-MXene-based electrocatalysts for enhanced electrocatalysis of overall water splitting Issue Information
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