在腐蚀实验中添加表面活性剂抑制剂的位置的重要性

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-04-02 DOI:10.5006/4514
Kushal Singla, Bruce Brown, S. Nešić
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引用次数: 0

摘要

使用有机表面活性剂缓蚀剂为油气生产和运输管道的内部腐蚀控制提供了一种经济有效的方法。利用电化学技术进行的缓蚀测量可用于根据稳态腐蚀速率评估缓蚀剂的功效。与时间相关的腐蚀行为可进一步用于量化抑制剂分子在金属上的吸附动力学,并可进一步整合到腐蚀预测工具的开发中。然而,在测试溶液中存在缓蚀剂的情况下,腐蚀速率测量对实验方法非常敏感,如果不严格遵循稳健的方法,通常很难实现可重复性。本研究讨论了实验室规模腐蚀实验中添加抑制剂位置的重要性。
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Importance of Location for Addition of Surfactant Inhibitors in Corrosion Experiments
Use of organic surfactant corrosion inhibitors provides an economical and effective way for internal corrosion control of oil and gas production and transportation pipelines. Corrosion inhibition measurements using electrochemical techniques can be used to evaluate the efficacy of corrosion inhibitors based on steady state corrosion rates. The corrosion behavior with respect to time can further be utilized to quantify adsorption kinetics of inhibitor molecules on metal and can further be integrated in the development of corrosion prediction tools. However, corrosion rates measurements can be very sensitive to experimental methodology in the presence of corrosion inhibitors in the test solution, and repeatability is often difficult to achieve if a robust methodology is not followed meticulously. In this study, the importance of the location of inhibitor addition in lab-scale corrosion experimentation is discussed.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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