Doan Huu Nhan, Huynh Ngoc Cong, Nguyen Ngoc Thanh Nha, Le Phuoc Hai, Nguyen Trong Toan, Hoang Luong Cuong, Sok Won Kim, Phuong V. Pham, Le T. Lu, Le Van Hieu, Top Khac Le
{"title":"退火诱导的氧化态转变、晶体形成、光学特性和纳米氧化钒的光催化活性","authors":"Doan Huu Nhan, Huynh Ngoc Cong, Nguyen Ngoc Thanh Nha, Le Phuoc Hai, Nguyen Trong Toan, Hoang Luong Cuong, Sok Won Kim, Phuong V. Pham, Le T. Lu, Le Van Hieu, Top Khac Le","doi":"10.1007/s11051-024-05994-5","DOIUrl":null,"url":null,"abstract":"<p>Vanadium has various oxidation states and multiple crystalline phases that make it interesting for various applications. The oxidation state transition and crystal formation of vanadium oxide (VO<sub>x</sub>) were affected by growth conditions and annealing temperatures. In this study, VO<sub>x</sub> nanopowders were prepared by hydrothermal method, and annealing-induced characterizations of VO<sub>x</sub> were analyzed. The morphologies, structures, composition, and optical properties of VO<sub>x</sub> were characterized by SEM, XRD, EDX, FTIR, and UV–Vis spectroscopy. The results demonstrated that the annealing temperature significantly affected the transition of oxide states from the VOOH and VO<sub>x</sub> clusters to V<sub>2</sub>O<sub>5</sub> nanoparticles and the crystal size from amorphous to 38.96 nm which led to an increase in the optical band gap from 2.28, 2.26 to 2.39 and 2.38 eV as increasing calcination temperature and enhanced photocatalytic activity under sunlight irradiation. The energy dispersive X-ray (EDX) spectra reveal that the percentage molar mass between vanadium and oxygen changes due to the oxidation state transition and the formation of oxygen vacancies in V<sub>2</sub>O<sub>5</sub>. The relation between nanoparticle size, oxidation state, and crystal size was clarified by comparing EDX and XRD spectra.</p>","PeriodicalId":653,"journal":{"name":"Journal of Nanoparticle Research","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Annealing-induced oxidation state transition, crystal formation, optical properties, and photocatalytic activity of vanadium oxide nanoparticles\",\"authors\":\"Doan Huu Nhan, Huynh Ngoc Cong, Nguyen Ngoc Thanh Nha, Le Phuoc Hai, Nguyen Trong Toan, Hoang Luong Cuong, Sok Won Kim, Phuong V. Pham, Le T. Lu, Le Van Hieu, Top Khac Le\",\"doi\":\"10.1007/s11051-024-05994-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Vanadium has various oxidation states and multiple crystalline phases that make it interesting for various applications. The oxidation state transition and crystal formation of vanadium oxide (VO<sub>x</sub>) were affected by growth conditions and annealing temperatures. In this study, VO<sub>x</sub> nanopowders were prepared by hydrothermal method, and annealing-induced characterizations of VO<sub>x</sub> were analyzed. The morphologies, structures, composition, and optical properties of VO<sub>x</sub> were characterized by SEM, XRD, EDX, FTIR, and UV–Vis spectroscopy. The results demonstrated that the annealing temperature significantly affected the transition of oxide states from the VOOH and VO<sub>x</sub> clusters to V<sub>2</sub>O<sub>5</sub> nanoparticles and the crystal size from amorphous to 38.96 nm which led to an increase in the optical band gap from 2.28, 2.26 to 2.39 and 2.38 eV as increasing calcination temperature and enhanced photocatalytic activity under sunlight irradiation. The energy dispersive X-ray (EDX) spectra reveal that the percentage molar mass between vanadium and oxygen changes due to the oxidation state transition and the formation of oxygen vacancies in V<sub>2</sub>O<sub>5</sub>. The relation between nanoparticle size, oxidation state, and crystal size was clarified by comparing EDX and XRD spectra.</p>\",\"PeriodicalId\":653,\"journal\":{\"name\":\"Journal of Nanoparticle Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-05-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Nanoparticle Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11051-024-05994-5\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Nanoparticle Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11051-024-05994-5","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Annealing-induced oxidation state transition, crystal formation, optical properties, and photocatalytic activity of vanadium oxide nanoparticles
Vanadium has various oxidation states and multiple crystalline phases that make it interesting for various applications. The oxidation state transition and crystal formation of vanadium oxide (VOx) were affected by growth conditions and annealing temperatures. In this study, VOx nanopowders were prepared by hydrothermal method, and annealing-induced characterizations of VOx were analyzed. The morphologies, structures, composition, and optical properties of VOx were characterized by SEM, XRD, EDX, FTIR, and UV–Vis spectroscopy. The results demonstrated that the annealing temperature significantly affected the transition of oxide states from the VOOH and VOx clusters to V2O5 nanoparticles and the crystal size from amorphous to 38.96 nm which led to an increase in the optical band gap from 2.28, 2.26 to 2.39 and 2.38 eV as increasing calcination temperature and enhanced photocatalytic activity under sunlight irradiation. The energy dispersive X-ray (EDX) spectra reveal that the percentage molar mass between vanadium and oxygen changes due to the oxidation state transition and the formation of oxygen vacancies in V2O5. The relation between nanoparticle size, oxidation state, and crystal size was clarified by comparing EDX and XRD spectra.
期刊介绍：
The objective of the Journal of Nanoparticle Research is to disseminate knowledge of the physical, chemical and biological phenomena and processes in structures that have at least one lengthscale ranging from molecular to approximately 100 nm (or submicron in some situations), and exhibit improved and novel properties that are a direct result of their small size.
Nanoparticle research is a key component of nanoscience, nanoengineering and nanotechnology.
The focus of the Journal is on the specific concepts, properties, phenomena, and processes related to particles, tubes, layers, macromolecules, clusters and other finite structures of the nanoscale size range. Synthesis, assembly, transport, reactivity, and stability of such structures are considered. Development of in-situ and ex-situ instrumentation for characterization of nanoparticles and their interfaces should be based on new principles for probing properties and phenomena not well understood at the nanometer scale. Modeling and simulation may include atom-based quantum mechanics; molecular dynamics; single-particle, multi-body and continuum based models; fractals; other methods suitable for modeling particle synthesis, assembling and interaction processes. Realization and application of systems, structures and devices with novel functions obtained via precursor nanoparticles is emphasized. Approaches may include gas-, liquid-, solid-, and vacuum-based processes, size reduction, chemical- and bio-self assembly. Contributions include utilization of nanoparticle systems for enhancing a phenomenon or process and particle assembling into hierarchical structures, as well as formulation and the administration of drugs. Synergistic approaches originating from different disciplines and technologies, and interaction between the research providers and users in this field, are encouraged.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
