利用二茂锆(III)进行光诱导碳自由基生成

IF 1.4 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemistry Letters Pub Date : 2024-05-15 DOI:10.1093/chemle/upae095
Eisuke Ota, Kazuhiro Aida, Junichiro Yamaguchi
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引用次数: 0

摘要

随着光氧化还原化学的最新进展,出现了多种生成碳自由基的方法。本综述重点介绍了利用二茂锆(III)生成自由基的最新方法,二茂锆(III)是一种在有机合成中很少使用的物质。其中特别值得关注的是采用可见光照射的方法,这种方法可诱导烷基锆的 C-Zr 键均解,或激活光氧化催化剂以还原二茂锆(IV)。
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Harnessing Zirconocene (III) for Photoinduced Carbon Radical Generation
With recent advances in photoredox chemistry, a variety of methods for generating carbon radicals have emerged. This review highlights recent approaches for radical generation utilizing zirconocene(III), a species infrequently employed in organic syntheses. Of particular interest are methods employing visible light irradiation, which induce C–Zr bond homolysis of alkyl zirconium species or activate a photoredox catalyst to reduce zirconocene(IV).
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来源期刊
Chemistry Letters
Chemistry Letters 化学-化学综合
CiteScore
3.00
自引率
6.20%
发文量
260
审稿时长
1.2 months
期刊介绍: Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry
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