以高岭土为原料合成 NaX 型沸石并将其应用于洗涤剂生产的比较研究

I. Ekpe, H. Mgbemere, Lawal Ganiyu, Henry Ovri, Anna Lisa Sargent, Obioha Charles
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引用次数: 0

摘要

用作洗涤剂添加剂的沸石是用昂贵的化学品合成的,生产过程繁琐。在这项研究中,沸石是用更便宜且容易获得的高岭土合成的,可能用于洗涤剂生产。研究使用了尼日利亚奥贡州 Ajebo 和包奇州 Darazo 这两个产地的高岭土作为起始材料,同时使用湿法选矿和酸浸法提纯高岭土,并使用水热法合成沸石。化学分析证实了二氧化硅和氧化铝的存在,它们是合成沸石的前体材料。两种高岭土所需的二氧化硅和氧化铝含量的增加,以及作为杂质存在于高岭土中的不需要的氧化物含量的减少,都清楚地表明酸浸法是成功的。与用纯化学品合成的沸石相比,用这两种高岭土合成的沸石具有更好的水吸附能力和离子交换能力。这些结果表明,用高岭土合成的沸石有可能取代用化学品合成的价格昂贵的沸石,用于生产洗涤剂。
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A Comparative Study on the Synthesis of Type NaX Zeolite Prepared from Kaolin for Builder Application in Detergent Production
Zeolites being used as builders in detergents are synthesized from expensive chemicals with a cumbersome production process. In this study, zeolite was synthesized from cheaper and readily available kaolin for possible use in detergent production. Kaolin from two sources namely Ajebo, Ogun State and Darazo, Bauchi State, Nigeria was used as starting materials while wet beneficiation followed by acid leaching was used to purify the kaolin and hydrothermal process was used to synthesize the zeolite. The chemical analysis confirms the presence of silica and alumina which are the precursors materials for zeolite synthesis. An increase in the amounts of the desired silica and alumina for both kaolin accompanied by a reduction in the amounts of the undesired oxides present in the kaolin as impurities are clear indications that the acid leaching was successful. The zeolites synthesized from both kaolin shows better water adsorption capacity and ion exchange capacity compared to those reported for zeolite synthesized from pure chemicals, this ability makes zeolite more suitable for the production of detergent. These results are indications that zeolites synthesized from kaolin can serve as a possible replacement for the more expensive zeolite synthesized from chemicals used as builders in detergent production.
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