研究醋酸脲-三乙醇胺-水体系中各种成分的溶解特性

Eldor Khusanov, Zhamshid Shukhurov
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引用次数: 0

摘要

在这项工作中,为了合成新的生理活性物质,采用观察聚热法研究了醋酸脲三乙醇胺水三元体系中各组分在-43°C至18°C的宽浓度和温度范围内的溶解特性。绘制了所研究体系的溶解度图,并分离了所有物质醋酸脲、三乙醇胺、冰和新化合物С3Н8O3N2∙N(C2H4OH)3 醋酸脲三乙醇胺的结晶区域。采用化学分析方法确定了新物质 С3Н8O3N2∙N(C2H4OH)3 的成分。为了确定合成具有新的生理活性特性的С3Н8O3N2∙N(C2H4OH)3 醋酸脲乙醇铵的最佳条件,研究了在 60%、70% 和 80% 醋酸脲中加入三乙醇胺后溶液的流变特性。根据所研究体系的流变特性、рH 指标、溶液的密度和粘度以及折射率,构建了 "成分-特性 "图。在 60 % 的醋酸脲溶液中加入三乙醇胺,确定了合成新物质 С3Н8O3N2∙N(C2H4OH)3醋酸脲三乙醇胺的最佳条件。
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STUDY OF SOLUBILITY PROPERTIES OF COMPONENTS IN ACETATE UREA - TRIETHANOLAMINE - WATER SYSTEM
In this work, in order to synthesize new physiologically active substances, the solubility properties of the components in the acetate urea triethanolamine water ternary system were studied by observational polythermal method at a wide range of concentration and a temperature range from -43°C to 18°C. The solubility diagram of the studied system was constructed and the crystallization areas of all substances acetateurea, triethanolamine, ice and the new compound С3Н8O3N2∙N(C2H4OH)3 acetate ureatriethanolammonium were separated. The composition of the new substance С3Н8O3N2∙N(C2H4OH)3 was determined using the chemical analysis method. In order to determine optimal conditions for the synthesis of С3Н8O3N2∙N(C2H4OH)3 acetate ureatriethanolammonium, which has a new physiologically active property, the rheological properties of the solution were studied by adding triethanolamine to 60, 70 and 80 % acetateurea. A “composition-property” diagram was constructed based on the rheological properties of the studied system, the рH indicator, the density and viscosity of the solution, and the refractive index. The optimal conditions for the synthesis of the new substance С3Н8O3N2∙N(C2H4OH)3 acetate ureatriethanolammonium, obtained by the ratio of components, were determined by adding triethanolamine to a 60 % acetate urea solution.
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Journal of Chemical Technology and Metallurgy
Journal of Chemical Technology and Metallurgy Engineering-Industrial and Manufacturing Engineering
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1.40
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