氧化还原活性靛酚配体的镉(II)配合物：合成与结构

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-16 DOI:10.1134/S1070328423601309

E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin

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引用次数: 0

摘要

摘要合成了氧化还原两性 2,6-二(叔丁基)-4-((2-羟基苯基)亚氨基)环己-2,5-二烯酮配体 L1 和 L2 的Сd(II)配合物（加合物 I、II 和 III）。配位络合物 I、II 和 III 的结构由 X 射线衍射 (XRD) 确定（CIF 文件 CCDC 编号：1838319 (II) 和 1838310 (III)），并由 1Н、13С 和 113Cd NMR 光谱（络合物 I 和 III）和红外光谱数据证实。

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Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

The Сd(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L¹ and L² (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the ¹Н, ¹³С, and ¹¹³Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.