Hui-Yu Qin , Bing-Guang Zhang , Qiao-Zhen Sun , M. Weil (Editor)
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引用次数: 0
摘要
在标题化合物的晶体结构中，{[Co(C11H9NSO5)(C10H9N3)]0.5C3H7NO-H2O} n 或 {[Co(dmtb)(dpa)]-0.5DMF-H2O}n（dmtb2- = 5-[（二甲基氨基）硫氧甲氧基]-1,3-苯二甲酸酯，dpa = 4,4′-二吡啶基胺），出现了平行于 bc 平面延伸的周期性[Co(C11H9NSO5)(C10H9N3)] n 层组合。每一层都由扭曲的[CoO4N2]八面体构成，这些八面体通过 dmtb2- 和 dpa 配体的 μ 2 配位模式连接在一起。占据无序的水和二甲基甲酰胺（DMF）溶剂分子位于网络的空隙中，它们通过氢键相互作用与网络连接。
The crystal structure of the title compound shows a layered arrangement parallel to the bc plane where [CoO4N2] octahedra are linked by dmtb2– and dpa ligands.
In the crystal structure of the title compound, {[Co(C11H9NSO5)(C10H9N3)]0.5C3H7NO·H2O}n or {[Co(dmtb)(dpa)]·0.5DMF·H2O}n (dmtb2– = 5-[(dimethylamino)thioxomethoxy]-1,3-benzenedicarboxylate and dpa = 4,4′-dipyridylamine), an assembly of periodic [Co(C11H9NSO5)(C10H9N3)]n layers extending parallel to the bc plane is present. Each layer is constituted by distorted [CoO4N2] octahedra, which are connected through the μ2-coordination modes of both dmtb2– and dpa ligands. Occupationally disordered water and dimethylformamide (DMF) solvent molecules are located in the voids of the network to which they are connected through hydrogen-bonding interactions.
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